Industrial chemicals · Taylor, TX
Technical Data Sheet

Technical Data Sheet

Ammonium Bifluoride Flakes Technical Grade

Technical

Alliance Code
ammonium-bifluoride-flakes
確認日
2026-07-17
Revision
1.6
CAS番号
1341-49-7
UN番号
UN1727
危険有害性クラス・容器等級
8 · PG II
構造
2D chemical structure of Ammonium Bifluoride Flakes Technical Grade
構造・PubChem
グレード
Technical
注意喚起語
Danger
危険有害性
腐食性急性毒性H301 H314
正式輸送品名
Ammonium hydrogendifluoride, solid
Last reviewed 2026-07-17 by Andre Taki, Chief Commercial Officer.

Identity & Composition

製品名
Ammonium Bifluoride Flakes Technical Grade
Alliance Code
ammonium-bifluoride-flakes
グレード
Technical
濃度
—
CAS番号
1341-49-7PubChem
化学式
NH4HF2Adjudicated
分子量
57.04 g/molAdjudicated
製品種別
Pure substance

Specifications

TestSpecificationTypicalMethodSource
Assay (NH₄HF₂)≥96.0%98.3%—Interpreted
Ammonium fluoride (NH4F)4.0 % maximum1.0 %—Interpreted
Antimony (Sb)10 ppm maximum0.21 ppm—Interpreted
Arsenic (As)10 ppm maximum0.23 ppm—Interpreted
Chloride (Cl)30 ppm maximum10.8 ppm—Interpreted
Copper (Cu)30 ppm maximum0.38 ppm—Interpreted
Fluorine (as F)65.0 % minimum66.0 %—Interpreted
Iron (Fe)10 ppm maximum2.8 ppm—Interpreted
Lead (Pb)5.0 ppm maximum0.11 ppm—Interpreted
Nickel (Ni)10 ppm maximum1.1 ppm—Interpreted
Silica (SiO2)100 ppm maximum36 ppm—Interpreted
Sulfate (SO4)100 ppm maximum27 ppm—Interpreted
Water (H2O)1000 ppm maximum507 ppm—Interpreted
Non-volatile matter (residue after ignition)0.10 % maximum0.011 %Gravimetric, ignition at 600 °C in platinumInterpreted

Values are reproduced from the current product reference. Source labels do not by themselves establish a supplier guarantee or a test result for your lot. Confirm applicable acceptance limits and request lot-specific documentation.

Available GradesSame CAS, alternate grades and concentrations

グレード濃度Typical AssaySKUTDS
This grade Technical——currentcurrent
ACS——ammonium-bifluoride-flakes-acs-gradeView TDS →

Typical assay shown is the rolling-window mean from the sibling product's most recent lots. Grade selection drives downstream end-use — verify the sibling grade matches your specification before substitution.

物理的及び化学的性質

Property値Source
外観White crystalline flakesAdjudicated
形状SolidPublished reference
臭いOdorless to slightly pungentAdjudicated
pH4.0–6.5 (5% aqueous solution, 25 °C)Adjudicated
比重1.50 at 20 °C (water = 1)Adjudicated
密度1.5 at 68 °F (USCG, 1999) - Denser than water; will sinkPublished reference
沸点Decomposes at about 230–240 °C (446–464 °F) before boilingAdjudicated
融点125–126 °C (257–259 °F)Adjudicated
引火点該当しないAdjudicated
蒸気圧About 0.75 mmHg (1 hPa) at 20 °CAdjudicated
Solubility (water)Very soluble in water (about 600 g/L at 20 °C); slightly soluble in ethanol (1.7% at 25 °C)Adjudicated

Materials of Construction

MaterialRatingConditionsSource
glass / silicate-containing materialsNot recommended—lab.solstice.com
glassNot recommended—lab.solstice.com
silicate-containing materialsNot recommended—lab.solstice.com

Compatibility is drawn from published manufacturer and supplier documentation for this product; each rating is sourced. Confirm against your specific duty cycle before equipment selection.

Regulatory & Transport

DOT / 49 CFR

国連番号
UN172749 CFR 172.101
危険有害性クラス
8Adjudicated
容器等級
IIAdjudicated
正式輸送品名
Ammonium hydrogendifluoride, solidAdjudicated

GHS / OSHA HCS 2024

注意喚起語
DangerAdjudicated
H-Codes (Hazard Statements)
H301, H314Adjudicated
P-Codes (Precautionary Statements)
P260, P264, P270, P280, P301+P310, P301+P330+P331, P303+P361+P353, P304+P340, P305+P351+P338, P310, P321, P330, P363, P405, P501Adjudicated

許容濃度

OSHA PEL (29 CFR 1910.1000)
2.5 mg/m³ TWA (F)Adjudicated
ACGIH TLV
2.5 mg/m³ TWA (fluorides, as F); BEI fluoride in urine 2 mg/L prior to shift, 3 mg/L end of shiftAdjudicated
NIOSH REL
2.5 mg/m³ TWA (F)Adjudicated
NIOSH IDLH
250 mg/m³ (F)Adjudicated

輸送情報は発行時点の49 CFR 172.101の照会結果を反映しています。データ出典:REL/IDLHはNIOSH Pocket Guide、PELはOSHA Zテーブル。出荷に関わる重要な判断の前に、必ず最新の規制本文で確認してください。

Health & Fire Hazard

Acute Toxicology

LD₅₀ Oral (rat)
130 mg/kg (rat, OECD 401)Adjudicated

急性毒性値はSDS第11項またはNIOSH RTECSによる。

Supplier Qualification Packet

One zipped download containing the TDS, SDS, latest lot COA (when available), and a fresh Letter of Continuing Guaranty for Ammonium Bifluoride Flakes Technical Grade. Every file included is SHA-256 hashed and listed in a manifest your QA team can audit.

Download audit packet

Applications

  • Fluoride source for etching, surface treatment and chemical processing where controlled fluoride activity is requiredlabproinc.com
  • Glass and silica etching, surface treatment, materials science research, analytical and laboratory chemistry, metallurgical processing and chemical manufacturinglabproinc.com
  • Hydraulic fracturing fluids and industrial use (supplier SDS states this as the recommended use)mubychem.com

Applications are drawn from published manufacturer and supplier documentation; each is sourced. Suitability for a specific use is the buyer's to confirm.

Storage & Handling

Recommended Storage
酸、塩基および湿気を避け、涼しく乾燥した換気の良い場所で、密閉した元のポリエチレン容器に保管すること。ガラスまたは金属製の容器には絶対に保管しないこと。施錠して保管すること。Adjudicated
Handling Precautions
Use in ventilation or with respiratory protection — vapour is the primary exposure. Chemical splash goggles and gloves. Open and transfer cool; pressure can build in warm sealed containers. Neutralization with acid is exothermic.Class-level guidance — not product-specific; the SDS controls.
Incompatibilities
酸類(フッ化水素ガスを発生);強塩基(アンモニアを発生);強酸化剤;ガラス、セラミックス、ならびにアルミニウムおよびマグネシウムなどの軽金属(侵される);水分。Adjudicated
Shelf Life
Consult Technical Services for product-specific shelf life

For full hazard, PPE, and emergency response guidance, refer to the Safety Data Sheet (SDS) for this product. The SDS controls in all cases where guidance differs.

Packaging & Logistics

Shipping Description (US DOT)

UN1727, Ammonium hydrogendifluoride, solid, 8, PG II

Sourced from 49 CFR 172.101. Confirm against shipping documents and carrier requirements before tender.

NMFC Class
60
Placard
Corrosive
容器等級
PG II

Revision History

Last reviewed 2026-07-17 by Andre Taki, Chief Commercial Officer, DOT Hazmat–certified (49 CFR 172.704).

VersionDateChangeTrigger
1.62026-10-08Canonical data updated: 25 fields changed via the provenance/adjudication pipeline.
  • ghsClassification· canonical change (coa.data_provenance / adjudication)
  • hazard_h_codes· canonical change (coa.data_provenance / adjudication)
  • hazard_p_codes· canonical change (coa.data_provenance / adjudication)
  • formula· canonical change (coa.data_provenance / adjudication)
  • molecularWeight· canonical change (coa.data_provenance / adjudication)
  • synonyms· canonical change (coa.data_provenance / adjudication)
  • restrictions_on_use· canonical change (coa.data_provenance / adjudication)
  • odor· canonical change (coa.data_provenance / adjudication)
  • flashPoint· canonical change (coa.data_provenance / adjudication)
  • meltingPoint· canonical change (coa.data_provenance / adjudication)
  • boilingPoint· canonical change (coa.data_provenance / adjudication)
  • decompositionTemperature· canonical change (coa.data_provenance / adjudication)
  • vaporPressure· canonical change (coa.data_provenance / adjudication)
  • specificGravity· canonical change (coa.data_provenance / adjudication)
  • solubility· canonical change (coa.data_provenance / adjudication)
  • oel_acgih_tlv· canonical change (coa.data_provenance / adjudication)
  • oel_other· canonical change (coa.data_provenance / adjudication)
  • incompatible_materials· canonical change (coa.data_provenance / adjudication)
  • conditions_to_avoid· canonical change (coa.data_provenance / adjudication)
  • hazardous_decomposition_products· canonical change (coa.data_provenance / adjudication)
  • storage_precautions· canonical change (coa.data_provenance / adjudication)
  • rcra_waste_codes· canonical change (coa.data_provenance / adjudication)
  • cercla_rq· canonical change (coa.data_provenance / adjudication)
  • recommended_use· canonical change (coa.data_provenance / adjudication)
  • pH· canonical change (coa.data_provenance / adjudication)
canonical_change
1.52026-10-05Canonical data updated: 3 fields changed via the provenance/adjudication pipeline.
  • oel_osha_pel· canonical change (coa.data_provenance / adjudication)
  • oel_niosh_rel· canonical change (coa.data_provenance / adjudication)
  • oel_idlh· canonical change (coa.data_provenance / adjudication)
canonical_change
1.42026-09-30Canonical data updated: 3 fields changed via the provenance/adjudication pipeline.
  • boilingPoint· canonical change (coa.data_provenance / adjudication)
  • meltingPoint· canonical change (coa.data_provenance / adjudication)
  • appearance· canonical change (coa.data_provenance / adjudication)
canonical_change
1.32026-08-05Canonical data updated: 4 fields changed via the provenance/adjudication pipeline.
  • hazardClass· canonical change (coa.data_provenance / adjudication)
  • packingGroup· canonical change (coa.data_provenance / adjudication)
  • signalWord· canonical change (coa.data_provenance / adjudication)
  • unNumber· canonical change (coa.data_provenance / adjudication)
canonical_change
1.22026-07-22Canonical data updated: 2 fields changed via the provenance/adjudication pipeline.
  • dotSubsidiaryHazardClass· canonical change (coa.data_provenance / adjudication)
  • dotProperShippingName· canonical change (coa.data_provenance / adjudication)
canonical_change
1.12026-07-17Canonical data re-verified: 5 fields updated against independent vendor SDSs, CLP Annex VI, 49 CFR, and OSHA HazCom 2024 (GHS classification, hazard/precautionary codes, signal word, physical properties as applicable).
  • countryOfOrigin· canonical adjudication / reground (coa.data_provenance)
  • ghsClassification· canonical adjudication / reground (coa.data_provenance)
  • hazard_h_codes· canonical adjudication / reground (coa.data_provenance)
  • hazard_p_codes· canonical adjudication / reground (coa.data_provenance)
  • hsCode· canonical adjudication / reground (coa.data_provenance)
canonical_change
1.02026-05-20Initial URL-first TDS published from canonical chemistry registry.initial

This Technical Data Sheet is provided for technical reference. The Safety Data Sheet (SDS) controls in all cases where guidance differs. Values reflect Alliance Chemical canonical data at time of generation; subsequent revisions are recorded in the Revision History above.