Denatured Alcohol 200 Proof 3A Technical Grade

Product Identifier

Denatured Alcohol 200 Proof 3A Technical Grade

Grade

Technical

CAS Number

64-17-5

Chemical Formula

C2H6O

Molecular Weight

46.07 g/mol

Manufacturer

Alliance Chemical
204 South Edmond Street, Taylor, TX 76574

Emergency Phone

Chemtel 1-800-255-3924 (24/7)

Synonyms

SDA 3-A; specially denatured alcohol formula 3-A; methanol-denatured ethanol

Recommended Use

Industrial solvent and cleaning agent; extraction; formulation of cleaners, coatings, inks and personal-care products under TTB rules.

Restrictions on Use

Specially denatured alcohol (TTB Formula 3-A, 27 CFR Part 21): not for beverage or internal use. Contains methanol — swallowing it can cause blindness or death, and it cannot be made non-poisonous.

Classification

• Flammable liquids, Category 2
• Serious eye damage/eye irritation, Category 2A
• Specific target organ toxicity, single exposure, Category 2

Signal Word

Danger

Hazard Statements

• H225Highly flammable liquid and vapor
• H319Causes serious eye irritation
• H371May cause damage to organs

Precautionary Statements

• P210Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
• P233Keep container tightly closed.
• P240Ground and bond container and receiving equipment.
• P241Use explosion-proof electrical, ventilating, and lighting equipment.
• P242Use non-sparking tools.
• P243Take precautionary measures against static discharge.
• P260Do not breathe dust, fume, gas, mist, vapors or spray.
• P264Wash hands and face thoroughly after handling.
• P270Do not eat, drink or smoke when using this product.
• P280Wear protective gloves, protective clothing, and eye/face protection.
• P303+P361+P353IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower.
• P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
• P308+P311IF exposed or concerned: Call a POISON CENTER or doctor.
• P337+P313If eye irritation persists: Get medical advice or attention.
• P370+P378In case of fire: Use alcohol-resistant foam, CO2 or dry chemical powder to extinguish.
• P403+P235Store in a well-ventilated place. Keep cool.
• P405Store locked up.
• P501Dispose of contents and container in accordance with local, regional, national, and international regulations.

Classification, hazard (H) and precautionary (P) statements and pictograms per OSHA HCS 2024 (29 CFR 1910.1200, Appendices A–C), aligned with GHS Rev. 7.

Concentrations are nominal; lot-specific values appear on the Certificate of Analysis. Components not contributing to classification are omitted.

Eyes

Rinse with plenty of water for at least 15 minutes. Remove contact lenses if present and easy to do. Continue rinsing. Seek medical attention immediately.

Skin

Immediately flush with plenty of water for at least 15 minutes while removing contaminated clothing. Wash with soap. Get medical attention immediately.

Inhalation

Move person to fresh air and keep comfortable for breathing. If breathing is difficult, give oxygen. If not breathing, give artificial respiration. Get medical attention immediately.

Ingestion

Do Not Induce Vomiting! Never give anything by mouth to an unconscious person. If conscious, wash out mouth with water. Get medical attention immediately.

Most Important Symptoms and Effects

• Eye contact causes irritation: redness, pain and tearing.
• A single exposure may damage organs.

Immediate Medical Attention and Special Treatment

• Treat symptomatically. Get medical attention if symptoms develop or persist.

Suitable Extinguishing Media

Alcohol-resistant foam, CO2, dry chemical powder. Water spray may be used to cool fire-exposed containers.

Unsuitable Extinguishing Media

Do not use a solid water stream — may scatter and spread fire.

Specific Hazards Arising from the Chemical

Vapors are heavier than air and may form explosive mixtures with air; they can travel to a source of ignition and flash back. Containers may rupture when heated.

Protective Equipment

Wear self-contained breathing apparatus and full protective clothing.

Hazardous Combustion Products

Carbon monoxide and carbon dioxide on combustion; formaldehyde from incomplete combustion of methanol.

Personal Precautions

Use PPE as described in Section 8. Ensure adequate ventilation. Evacuate personnel to safe areas.

Hazard-Specific Precautions

Eliminate all ignition sources. Use non-sparking tools and explosion-proof equipment; ground and bond containers during cleanup.

Environmental Precautions

Prevent leakage or spillage from entering drains, sewers, or waterways.

Containment & Cleanup

Absorb with inert material. Collect in appropriate waste container. Dispose per applicable regulations.

Safe Handling

Use with adequate ventilation. Avoid contact with skin, eyes, and clothing. Wash thoroughly after handling. Keep container closed when not in use.

Safe Storage

Store in a cool, dry, well-ventilated area away from heat, sparks, and open flame. Keep away from incompatible materials (see Section 10). Keep containers tightly closed. Ground and bond containers when transferring material.

Specific Storage Precautions

Keep containers tightly closed in a cool, dry, well-ventilated flammables area away from heat, sparks, open flame and direct sunlight. Keep in fireproof surroundings separated from strong oxidizers. Do not store above 49 °C (120 °F). Ground and bond containers when transferring.

Occupational Exposure Limits

Engineering Controls

Use adequate ventilation. Provide eyewash stations and quick-drench showers accessible to areas of use.

Eye/Face Protection

Wear chemical safety goggles or face shield.

Skin Protection

Wear chemical-resistant gloves and protective clothing.

Respiratory Protection

Use a NIOSH-approved respirator with organic vapor cartridges. For confined spaces or exposures above the OEL, use supplied-air respiratory protection.

Exposure limits sourced from NIOSH Pocket Guide, OSHA 29 CFR 1910.1000 and ACGIH TLVs.

Appearance

Clear, colorless liquid

Odor

Alcohol-like odor

Odor Threshold

No data available

pH

No data available

Melting Point / Freezing Point

About -114 °C (-173 °F) (ethanol)

Boiling Point

About 78 °C (172–173 °F) (ethanol)

Flash Point

13–16 °C (55–61 °F), closed cup

Evaporation Rate

No data available

Flammability (solid, gas)

No data available

Upper/Lower Flammability or Explosive Limits

LEL 3.3% / UEL 19% (v/v in air, ethanol)

Vapor Pressure

43–45 mmHg at 20 °C

Vapor Density

1.6 (air = 1)

Relative Density

0.79–0.80 at 15.5–20 °C (water = 1)

Solubility

Completely miscible with water

Partition Coefficient (n-octanol/water)

No data available

Auto-ignition Temperature

No data available

Decomposition Temperature

No data available

Viscosity

About 1.1 mm²/s at 40 °C

Particle Characteristics

Not applicable

Form

Liquid

Density

0.79 at 68 °F (USCG, 1999) - Less dense than water; will float

Values shown reflect product-specific canonical data. Lot-specific ranges may vary; see the Certificate of Analysis for the shipped lot.

Reactivity

Not reactive under normal conditions of use and storage.

Chemical Stability

Stable under recommended storage conditions.

Possibility of Hazardous Reactions

None under normal processing conditions.

Conditions to Avoid

Heat, sparks, open flame, static discharge and other ignition sources. Burns with a pale, nearly invisible flame.

Incompatible Materials

Strong oxidizing agents (peroxides, nitric acid, perchlorates, hypochlorites); strong acids; alkali metals; ammonia; acid anhydrides.

Hazardous Decomposition Products

Carbon monoxide and carbon dioxide on combustion; formaldehyde from incomplete combustion of methanol.

See below for route-specific acute toxicity data.

Likely Routes of Exposure

Inhalation, skin contact, eye contact, ingestion.

Symptoms

• Eye contact causes irritation: redness, pain and tearing.
• A single exposure may damage organs.

Delayed and Chronic Effects

• No delayed or chronic effects identified beyond the classification in Section 2.

Carcinogen Classification

Scope: the IARC and NTP listings apply to ethanol in alcoholic beverages, not to ethanol used as a solvent.

Ecotoxicity

Algae ErC50: ~ 1450 mg/L (Microcystis aeruginosa — cell-multiplication inhibition threshold); Fish LC50: 11200 mg/L (24 h, Oncorhynchus mykiss (flow-through, 10 °C); 24-h window)

Persistence & Degradability

Not persistent; rapid aerobic biodegradation — Readily biodegradable (89% ThBOD in 2 wk, activated sludge)

Bioaccumulative Potential

log Kow −0.31, BCF 3 (estimated; low)

Mobility in Soil

Very high soil mobility (log Koc 0.20)

Dispose of contents/container in accordance with applicable federal, state, and local regulations. Do not dispose of into drains or waterways.

EPA RCRA Waste Codes

D001 (ignitable). Not U154: methanol is a denaturant, not the sole active ingredient.

If discarded, this material may be an ignitable hazardous waste (EPA RCRA D001, 40 CFR 261.21(a)(1): flash point below 60 °C; aqueous solutions with less than 24% alcohol by volume are excluded). The waste generator must make the final hazardous-waste determination.

US DOT (49 CFR)

UN Number

UN1987

Proper Shipping Name

Alcohols, n.o.s.

Hazard Class

3

Packing Group

II

Additional US DOT Requirements

Inner packagings of 1 L or less may ship as Limited Quantity (49 CFR 173.150(b)). Not a marine pollutant.

IMDG / IATA classifications may differ from US DOT. Verify current regulations before international shipment.

CERCLA Reportable Quantity (RQ)

Methanol (CAS 67-56-1) 5,000 lb (2,270 kg), about 104,000 lb of this product at 4.8% methanol; no single package reaches it. Methanol is EPCRA Section 313 (TRI) listed, de minimis 1.0%.

SARA 311/312 hazard categories correspond to the GHS classification in Section 2. Data retrieved as of: California Proposition 65 2026-10-02; US EPA TSCA Active Inventory 2026-10-02; EPCRA SARA 313 (TRI) 2026-10-02.

Revision Date

2026-10-13

Format

16-section format per OSHA HCS 2024 (29 CFR 1910.1200, Appendix D), aligned with GHS Rev. 7.