Technical Data Sheet

Ammonium Hydroxide 20% ACS Grade

CAS Number
1336-21-6
Alliance Code
ammonium-hydroxide-20-acs-grade
Generated
2026-06-02
Last reviewed 2026-05-20 by Hossein Taki, Vice President.

1. Identity & Composition

Product Name
Ammonium Hydroxide 20% ACS Grade
Alliance Code
ammonium-hydroxide-20-acs-grade
Grade
Concentration
CAS Number
1336-21-6PubChem
Formula
H5NOPubChem
Molecular Weight
35.046PubChem
Product Type
solution

Available GradesSame CAS, alternate grades and concentrations

GradeConcentrationTypical AssaySKUTDS
This grade currentcurrent
ACS Grade29%ammonium-hydroxide-29-acs-gradeView TDS →
Technical Grade29%ammonium-hydroxide-29-technical-gradeView TDS →
ammonium-hydroxide-10-acs-gradeView TDS →
ammonium-hydroxide-10-technical-gradeView TDS →
ammonium-hydroxide-15-acs-gradeView TDS →
ammonium-hydroxide-15-technical-gradeView TDS →
ammonium-hydroxide-20-technical-gradeView TDS →
ammonium-hydroxide-5-acs-gradeView TDS →
ammonium-hydroxide-5-technical-gradeView TDS →

Typical assay shown is the rolling-window mean from the sibling product's most recent lots. Grade selection drives downstream end-use — verify the sibling grade matches your specification before substitution.

Materials of Construction

MaterialRatingMax T (°C)NotesSource
Buna-N (NBR)
elastomer
Fair40Limited service lifeCole-Parmer Chemical Compatibility
EPDM
elastomer
Excellent90Preferred elastomerCole-Parmer Chemical Compatibility
Viton (FKM)
elastomer
PoorNot recommended above 25%Cole-Parmer Chemical Compatibility
PTFE
fluoropolymer
Excellent200Lining and gasketsCole-Parmer Chemical Compatibility
Borosilicate Glass
glass ceramic
Fair25Attacked above 30 % or elevated temp; avoid long-term service.Cole-Parmer Chemical Compatibility
304 stainless steel
metal
Good80Acceptable for dilute causticCole-Parmer Chemical Compatibility
316 stainless steel
metal
Excellent95Standard caustic serviceCole-Parmer Chemical Compatibility
316L Stainless Steel
metal
Excellent80Preferred metal for caustic service.NACE TM0177
Aluminium
metal
Not recommendedRapid attack; generates hydrogenCole-Parmer Chemical Compatibility
Carbon steel
metal
Good50Acceptable to 50 °C; caustic embrittlement aboveCole-Parmer Chemical Compatibility
Carbon Steel
metal
Good60Acceptable below 70 °C; caustic embrittlement risk above.NACE Caustic Service Limits
Nickel
metal
Excellent100Preferred for high-temperature causticCole-Parmer Chemical Compatibility
Zinc / galvanized steel
metal
Not recommendedRapid corrosionCole-Parmer Chemical Compatibility
HDPE
thermoplastic
Excellent60Standard drum / IBC materialCole-Parmer Chemical Compatibility
Polypropylene
thermoplastic
Excellent80Excellent caustic service to 50 %.Cole-Parmer Chemical Compatibility
PP
thermoplastic
Excellent80Preferred for elevated temperatureCole-Parmer Chemical Compatibility
PVC
thermoplastic
Good40Acceptable for ambient serviceCole-Parmer Chemical Compatibility

Ratings reflect the service envelope (concentration × temperature) shown. Always confirm against your specific duty cycle and contact-time before equipment selection. The most cautious rating across overlapping references is shown.

Materials Selection Tool

Showing 17 of 17 materials compatible at the selected envelope.

MaterialRatingMax T (°C)Notes
Buna-N (NBR)
elastomer
Fair40Limited service life
EPDM
elastomer
Excellent90Preferred elastomer
Viton (FKM)
elastomer
PoorNot recommended above 25%
PTFE
fluoropolymer
Excellent200Lining and gaskets
Borosilicate Glass
glass ceramic
Fair25Attacked above 30 % or elevated temp; avoid long-term service.
304 stainless steel
metal
Good80Acceptable for dilute caustic
316 stainless steel
metal
Excellent95Standard caustic service
316L Stainless Steel
metal
Excellent80Preferred metal for caustic service.
Aluminium
metal
Not recommendedRapid attack; generates hydrogen
Carbon steel
metal
Good50Acceptable to 50 °C; caustic embrittlement above
Carbon Steel
metal
Good60Acceptable below 70 °C; caustic embrittlement risk above.
Nickel
metal
Excellent100Preferred for high-temperature caustic
Zinc / galvanized steel
metal
Not recommendedRapid corrosion
HDPE
thermoplastic
Excellent60Standard drum / IBC material
Polypropylene
thermoplastic
Excellent80Excellent caustic service to 50 %.
PP
thermoplastic
Excellent80Preferred for elevated temperature
PVC
thermoplastic
Good40Acceptable for ambient service

Regulatory & Transport

DOT / 49 CFR

UN Number
UN2672Vendor Label
Hazard Class
8Adjudicated
Packing Group
IIIAdjudicated
Proper Shipping Name
Ammonia solutionAdjudicated

GHS / OSHA HazCom 2012

Signal Word
DangerAdjudicated
H-Codes (Hazard Statements)
H290, H314, H335, H400ECHA CLP Annex VI
P-Codes (Precautionary Statements)
P234, P260, P261, P264, P271, P273, P280, P301+P330+P331, P303+P361+P353, P304+P340, P305+P351+P338, P310, P321, P363, P391, P403+P233, P405, P501ECHA CLP Annex VI

Occupational Exposure Limits

OSHA PEL (29 CFR 1910.1000)
unknown
ACGIH TLV
unknown
NIOSH REL
unknown
NIOSH IDLH
unknown

Transport descriptions reflect 49 CFR 172.101 lookup at time of publication. Sourced data: ECHA CLP Annex VI for harmonised classifications, NIOSH Pocket Guide for REL/IDLH, OSHA Z-Tables for PEL. Always verify against the latest regulatory text before shipment-critical decisions.

Supplier Qualification Packet

One zipped download containing the TDS, SDS, latest lot COA (when available), and a fresh Letter of Continuing Guaranty for Ammonium Hydroxide 20% ACS Grade. Every file included is SHA-256 hashed and listed in a manifest your QA team can audit.

Download audit packet

Application Guidance

Ammonium Hydroxide 20% ACS Grade is a strong base used for pH control, saponification, and chemical manufacturing.

  • pH adjustment and neutralization
  • Saponification and detergent manufacturing
  • Pulp and paper processing
  • Water treatment and softening
  • Chemical synthesis (caustic-driven reactions)

Highly exothermic when diluted — control mixing rate and temperature. Hygroscopic; protect from atmospheric moisture and CO2.

Storage & Handling

Recommended Storage
Cool, dry, well-ventilated area in compatible containers (HDPE, lined steel — not aluminium). Tightly sealed; protect from atmospheric moisture and CO2. Segregate from acids and oxidizers.
Handling Precautions
Use full PPE including chemical splash goggles and alkali-resistant gloves. Add base to water slowly with stirring. Highly exothermic dilution.
Incompatibilities
Acids (violent neutralization), aluminium, zinc, tin (generates hydrogen gas), halogens, organic nitro compounds.
Shelf Life
24 months from date of manufacture in sealed, original packaging

For full hazard, PPE, and emergency response guidance, refer to the Safety Data Sheet (SDS) for this product. The SDS controls in all cases where guidance differs.

Packaging & Logistics

Shipping Description (US DOT)

UN2672, Ammonia solution, 8, PG III

Sourced from 49 CFR 172.101. Confirm against shipping documents and carrier requirements before tender.

NMFC Class
65
Placard
Corrosive
Packing Group
PG III

Revision History

Last reviewed 2026-05-20 by Hossein Taki, Vice President (Vice President, Alliance Chemical · CAGE Code 1LT50 · DOT Hazmat Registrant #2188383).

VersionDateChangeTrigger
1.02026-05-20Initial URL-first TDS published from canonical chemistry registry.initial

This Technical Data Sheet is provided for technical reference. The Safety Data Sheet (SDS) controls in all cases where guidance differs. Values reflect Alliance Chemical canonical data at time of generation; subsequent revisions are recorded in the Revision History above.

Ammonium Hydroxide 20% ACS Grade — Technical Data Sheet | Alliance Chemical