Industrial chemicals · Taylor, TX
Technical Data Sheet

Technical Data Sheet

Ammonium Hydroxide 20% ACS Grade

ACS · 20%

Alliance Code
ammonium-hydroxide-20-acs-grade
Reviewed
2026-07-17
Revision
1.8
CAS number
1336-21-6
UN number
UN2672
Hazard class · packing group
8 · PG III
Structure
2D chemical structure of Ammonium Hydroxide 20% ACS Grade
Structure · PubChem
Grade
ACS · 20%
Signal word
Danger
Hazards
CorrosiveIrritant / harmfulEnvironmental hazardH314 H335 H400
Proper shipping name
Ammonia solution, relative density between 0.880 and 0.957 at 15 degrees C in water, with more than 10 percent but not more than 35 percent ammonia
Last reviewed 2026-07-17 by Andre Taki, Chief Commercial Officer.

Identity & Composition

Product Name
Ammonium Hydroxide 20% ACS Grade
Alliance Code
ammonium-hydroxide-20-acs-grade
Grade
ACS
Concentration
20%
CAS Number
1336-21-6PubChem
Formula
—PubChem
Molecular Weight
—PubChem
Product Type
Solution

Specifications

TestSpecificationTypicalMethodSource
Assay (NH3)19.7 - 20.3 %20.01 %TitrationInterpreted
Carbon dioxide (CO2)0.0014% max0.00043 %—Interpreted
Chloride (Cl)0.47 ppm max0.12 ppm—Interpreted
Heavy metals (as Pb)0.35 ppm max0.041 ppm—Interpreted
Iron (Fe)0.14 ppm max0.016 ppm—Interpreted
Nitrate (NO3)1.5 ppm max0.23 ppm—Interpreted
Phosphate (PO4)1.7 ppm max0.081 ppm—Interpreted
Residue after ignition0.0014 % max0.00026 %—Interpreted
Sulfur compounds (as SO4)1.4 ppm max0.23 ppm—Interpreted
Substances reducing permanganateTo pass TestPasses test—Interpreted
Composition20 % ammonium hydroxide in deionized water, by weightConformsBy formulation; confirmed by specific gravityInterpreted

Values are reproduced from the current product reference. Source labels do not by themselves establish a supplier guarantee or a test result for your lot. Confirm applicable acceptance limits and request lot-specific documentation.

Available GradesSame CAS, alternate grades and concentrations

GradeConcentrationTypical AssaySKUTDS
This grade ACS20%—currentcurrent
ACS Grade29%—ammonium-hydroxide-29-acs-gradeView TDS →
Technical Grade29%—ammonium-hydroxide-29-technical-gradeView TDS →
Technical20%—ammonium-hydroxide-20-technical-gradeView TDS →
ACS15%—ammonium-hydroxide-15-acs-gradeView TDS →
Technical15%—ammonium-hydroxide-15-technical-gradeView TDS →
ACS10%—ammonium-hydroxide-10-acs-gradeView TDS →
Technical10%—ammonium-hydroxide-10-technical-gradeView TDS →
ACS5%—ammonium-hydroxide-5-acs-gradeView TDS →
Technical5%—ammonium-hydroxide-5-technical-gradeView TDS →

Typical assay shown is the rolling-window mean from the sibling product's most recent lots. Grade selection drives downstream end-use — verify the sibling grade matches your specification before substitution.

Physical & Chemical Properties

PropertyValueSource
AppearanceClear, colorless liquid with strong ammonia odorAdjudicated
ColorClear, ColorlessInterpreted
Boiling Point38°CAdjudicated
Melting Point-57.5°CAdjudicated

Materials of Construction

MaterialRatingConditionsSource
copper and copper alloysNot recommended—tannerind.com
aluminum alloysNot recommended—tannerind.com
galvanized surfacesNot recommended—tannerind.com
copper, copper alloys, aluminum alloys, and galvanized surfacesNot recommended—tannerind.com

Compatibility is drawn from published manufacturer and supplier documentation for this product; each rating is sourced. Confirm against your specific duty cycle before equipment selection.

Regulatory & Transport

DOT / 49 CFR

UN Number
UN2672Adjudicated
Hazard Class
8Adjudicated
Packing Group
IIIAdjudicated
Proper Shipping Name
Ammonia solution, relative density between 0.880 and 0.957 at 15 degrees C in water, with more than 10 percent but not more than 35 percent ammoniaAdjudicated

GHS / OSHA HCS 2024

Signal Word
DangerAdjudicated
H-Codes (Hazard Statements)
H314, H335, H400Adjudicated
P-Codes (Precautionary Statements)
P234, P260, P261, P264, P271, P273, P280, P301+P330+P331, P303+P361+P353, P304+P340, P305+P351+P338, P310, P321, P363, P391, P403+P233, P405, P501Adjudicated

Occupational Exposure Limits

OSHA PEL (29 CFR 1910.1000)
50 ppm TWAOSHA 29 CFR 1910.1000
ACGIH TLV
—no canonical
NIOSH REL
25 ppm TWA / 35 ppm STELNIOSH Pocket Guide
NIOSH IDLH
300 ppmNIOSH Pocket Guide

Transport descriptions reflect 49 CFR 172.101 lookup at time of publication. Sourced data: NIOSH Pocket Guide for REL/IDLH, OSHA Z-Tables for PEL. Always verify against the latest regulatory text before shipment-critical decisions.

Supplier Qualification Packet

One zipped download containing the TDS, SDS, latest lot COA (when available), and a fresh Letter of Continuing Guaranty for Ammonium Hydroxide 20% ACS Grade. Every file included is SHA-256 hashed and listed in a manifest your QA team can audit.

Download audit packet

Applications

  • Acid neutralizationtannerind.com
  • Used in the chemical and petroleum industries and in agriculture, resins, polymers, acid neutralization, water treatment, cogeneration NOx scrubbing and explosivestannerind.com
  • Feedstock for preparing other ammonium compounds such as urea, ammonium carbonate and ammonium sulfatelaballey.com
  • Laboratory solvent, pharmaceutical manufacturing, polymer manufacturing, household cleaning reagent, and food additive / acidity regulatorlaballey.com
  • Buffers, ceramics, collagen sausage casing, detergents, fertilizer, hair bleaching and hair colorants, I&I cleaners, ink, photographic chemistry, rayon, refrigeration, selective catalytic reduction (SCR), textiles and window cleanerchemceed.com
  • Reagent for compounding analytical test solutionsuspbpep.com

Applications are drawn from published manufacturer and supplier documentation; each is sourced. Suitability for a specific use is the buyer's to confirm.

Storage & Handling

Recommended Storage
Store tightly closed in a cool, well-ventilated area out of sunlight; open containers slowly, as pressure may build up. Use steel or polyethylene, never copper, brass, bronze, zinc or galvanized fittings. Keep away from bleach, acids and halogens.Adjudicated
Handling Precautions
Use in ventilation or with respiratory protection — vapour is the primary exposure. Chemical splash goggles and gloves. Open and transfer cool; pressure can build in warm sealed containers. Neutralization with acid is exothermic.Class-level guidance — not product-specific; the SDS controls.
Incompatibilities
Bleach and other hypochlorites, chlorine, bromine and iodine (toxic chloramines and explosive compounds); mercury, silver and silver oxide, gold (explosive compounds); strong acids (violent, heat); strong oxidizers. Corrodes copper, brass, bronze, zinc, galvanized surfaces and aluminum alloys.Adjudicated
Shelf Life
Consult Technical Services for product-specific shelf life

For full hazard, PPE, and emergency response guidance, refer to the Safety Data Sheet (SDS) for this product. The SDS controls in all cases where guidance differs.

Packaging & Logistics

Shipping Description (US DOT)

UN2672, Ammonia solution, relative density between 0.880 and 0.957 at 15 degrees C in water, with more than 10 percent but not more than 35 percent ammonia, 8, PG III

Sourced from 49 CFR 172.101. Confirm against shipping documents and carrier requirements before tender.

NMFC Class
65
Placard
Corrosive
Packing Group
PG III

Revision History

Last reviewed 2026-07-17 by Andre Taki, Chief Commercial Officer, DOT Hazmat–certified (49 CFR 172.704).

VersionDateChangeTrigger
1.82026-10-13Canonical data updated: 4 fields changed via the provenance/adjudication pipeline.
  • storage_precautions· canonical change (coa.data_provenance / adjudication)
  • incompatible_materials· canonical change (coa.data_provenance / adjudication)
  • conditions_to_avoid· canonical change (coa.data_provenance / adjudication)
  • hazardous_decomposition_products· canonical change (coa.data_provenance / adjudication)
canonical_change
1.72026-09-30Canonical data updated: 3 fields changed via the provenance/adjudication pipeline.
  • boilingPoint· canonical change (coa.data_provenance / adjudication)
  • meltingPoint· canonical change (coa.data_provenance / adjudication)
  • appearance· canonical change (coa.data_provenance / adjudication)
canonical_change
1.62026-08-27Canonical data updated: 3 fields changed via the provenance/adjudication pipeline.
  • oel_niosh_rel· canonical change (coa.data_provenance / adjudication)
  • oel_idlh· canonical change (coa.data_provenance / adjudication)
  • oel_osha_pel· canonical change (coa.data_provenance / adjudication)
canonical_change
1.52026-08-19Canonical data updated: 1 field changed via the provenance/adjudication pipeline.
  • unNumber· canonical change (coa.data_provenance / adjudication)
canonical_change
1.42026-08-05Canonical data updated: 3 fields changed via the provenance/adjudication pipeline.
  • hazardClass· canonical change (coa.data_provenance / adjudication)
  • packingGroup· canonical change (coa.data_provenance / adjudication)
  • unNumber· canonical change (coa.data_provenance / adjudication)
canonical_change
1.32026-07-22Canonical data updated: 1 field changed via the provenance/adjudication pipeline.
  • dotSubsidiaryHazardClass· canonical change (coa.data_provenance / adjudication)
canonical_change
1.22026-07-17Canonical data updated: 1 field changed via the provenance/adjudication pipeline.
  • dotProperShippingName· canonical change (coa.data_provenance / adjudication)
canonical_change
1.12026-07-17Canonical data re-verified: 6 fields updated against independent vendor SDSs, CLP Annex VI, 49 CFR, and OSHA HazCom 2024 (GHS classification, hazard/precautionary codes, signal word, physical properties as applicable).
  • countryOfOrigin· canonical adjudication / reground (coa.data_provenance)
  • ghsClassification· canonical adjudication / reground (coa.data_provenance)
  • hazard_h_codes· canonical adjudication / reground (coa.data_provenance)
  • hazard_p_codes· canonical adjudication / reground (coa.data_provenance)
  • hsCode· canonical adjudication / reground (coa.data_provenance)
  • signalWord· canonical adjudication / reground (coa.data_provenance)
canonical_change
1.02026-05-20Initial URL-first TDS published from canonical chemistry registry.initial

This Technical Data Sheet is provided for technical reference. The Safety Data Sheet (SDS) controls in all cases where guidance differs. Values reflect Alliance Chemical canonical data at time of generation; subsequent revisions are recorded in the Revision History above.