Industrial chemicals · Taylor, TX
Technical Data Sheet

Technical Data Sheet

Methyl Ethyl Ketone (MEK) Technical Grade

Technical

CAS Number
78-93-3
Alliance Code
methyl-ethyl-ketone-mek
Generated
2026-08-31
Revision
1.3
Reviewed
2026-06-18 · Andre Taki
2D chemical structure of Methyl Ethyl Ketone (MEK) Technical Grade
Structure · PubChem
Last reviewed 2026-06-18 by Andre Taki, DOT Hazmat Specialist.

Identity & Composition

Product Name
Methyl Ethyl Ketone (MEK) Technical Grade
Alliance Code
methyl-ethyl-ketone-mek
Grade
Technical
Concentration
CAS Number
78-93-3PubChem
Formula
C4H8OPubChem
Molecular Weight
72.11PubChem
Product Type
pure_substance

Specifications

TestSpecificationTypicalMethodSource
Purity99.5 % m/m min.99.9 % m/mASTM D2804Supplier specification
Acidity (as acetic acid)0.003 wt% max0.0005 wt%ASTM D1613Supplier specification
Non-volatile residue2 mg/100ml max0.3 mg/100mlASTM D1353Supplier specification
Total Alcohols0.5 %m/m max.0.02 %m/mASTM D2804Supplier specification
Water0.05 % m/m max.0.02 % m/mASTM D1364Supplier specification
alcohol impurities0.05 mass % max0.02 mass %Supplier specification
ethyl acetate0.15 Mass % max0.02 Mass %Supplier specification
acetone content0.1 mass % max0.02 mass %Supplier specification

Specification values are guaranteed limits. Typical values are representative of production lots and are not guaranteed. Lot-specific certificates of analysis ship with every order.

Available GradesSame CAS, alternate grades and concentrations

GradeConcentrationTypical AssaySKUTDS
This grade Technicalcurrentcurrent
ACS Grademethyl-ethyl-ketone-mek-acs-gradeView TDS →

Typical assay shown is the rolling-window mean from the sibling product's most recent lots. Grade selection drives downstream end-use — verify the sibling grade matches your specification before substitution.

Physical & Chemical Properties

PropertyValueSource
AppearanceClear and BrightSupplier specification
FormLiquidPublished reference
Color10 Pt-Co max.Supplier specification
OdorCharacteristic, non-residualInterpreted
Specific Gravity (20 °C)0.805 - 0.807Supplier specification
Density0.806 at 68 °F (USCG, 1999) - Less dense than water; will floatPublished reference
Boiling Point79.0 °C minSupplier specification
Melting Point-123.3 °F (NTP, 1992)Published reference
Flash Point26 °F (NTP, 1992)Published reference
Vapor Pressure77.5 mmHg at 68 °F ; 100 mmHg at 77.0 °F (NTP, 1992)Published reference
Solubility (water)greater than or equal to 100 mg/mL at 66 °F (NTP, 1992)Published reference
Refractive Index (nD 20)1.3790Vendor COA

Regulatory & Transport

DOT / 49 CFR

UN Number
UN119349 CFR 172.101
Hazard Class
3Adjudicated
Packing Group
IIAdjudicated
Proper Shipping Name
Ethyl methyl ketone or methyl ethyl ketoneAdjudicated

GHS / OSHA HazCom 2012

Signal Word
DangerAdjudicated
H-Codes (Hazard Statements)
H225, H319, H336, EUH066ECHA CLP Annex VI
P-Codes (Precautionary Statements)
P210, P233, P240, P241, P242, P243, P261, P264, P271, P280, P303+P361+P353, P304+P340, P305+P351+P338, P312, P337+P313, P370+P378, P403+P233, P403+P235, P405, P501ECHA CLP Annex VI

Occupational Exposure Limits

OSHA PEL (29 CFR 1910.1000)
200 ppm TWAOSHA 29 CFR 1910.1000
ACGIH TLV
no canonical
NIOSH REL
200 ppm TWA / 300 ppm STELNIOSH Pocket Guide
NIOSH IDLH
3000 ppmNIOSH Pocket Guide

Transport descriptions reflect 49 CFR 172.101 lookup at time of publication. Sourced data: ECHA CLP Annex VI for harmonised classifications, NIOSH Pocket Guide for REL/IDLH, OSHA Z-Tables for PEL. Always verify against the latest regulatory text before shipment-critical decisions.

Supplier Qualification Packet

One zipped download containing the TDS, SDS, latest lot COA (when available), and a fresh Letter of Continuing Guaranty for Methyl Ethyl Ketone (MEK) Technical Grade. Every file included is SHA-256 hashed and listed in a manifest your QA team can audit.

Download audit packet

Catalog EquivalentsCross-reference vs major chemical suppliers

Sigma-Aldrich

SKUGradeConc.MatchNotes
360473ACS Reagent99%ExactACS Reagent ≥99%

Cross-references are informational. Confirm against the manufacturer's current specification before substitution. Competitor trademarks are property of their respective owners.

Applications

  • Solvent for natural and synthetic resins, giving solutions with low viscosity and high solids contentwurthmachinery.com
  • Used widely as a solventlabdepotinc.com

Applications are drawn from published manufacturer and supplier documentation; each is sourced. Suitability for a specific use is the buyer's to confirm.

Storage & Handling

Recommended Storage
Cool, dry, well-ventilated area in original sealed containers. Refer to product SDS for material-specific guidance.Class-level guidance — not product-specific; the SDS controls.
Handling Precautions
Use standard chemical PPE — splash goggles, gloves, lab coat. Refer to SDS for hazard-specific PPE requirements.Class-level guidance — not product-specific; the SDS controls.
Incompatibilities
Consult the SDS for material-specific incompatibilities.Class-level guidance — not product-specific; the SDS controls.
Shelf Life
12 monthswurthmachinery.comProvided proper storage and handling precautions are taken

For full hazard, PPE, and emergency response guidance, refer to the Safety Data Sheet (SDS) for this product. The SDS controls in all cases where guidance differs.

Packaging & Logistics

Shipping Description (US DOT)

UN1193, Ethyl methyl ketone or methyl ethyl ketone, 3, PG II

Sourced from 49 CFR 172.101. Confirm against shipping documents and carrier requirements before tender.

NMFC Class
70
Placard
Flammable Liquid
Packing Group
PG II

Revision History

Last reviewed 2026-06-18 by Andre Taki, DOT Hazmat Specialist.

VersionDateChangeTrigger
1.32026-08-05Canonical data updated: 4 fields changed via the provenance/adjudication pipeline.
  • hazardClass· canonical change (coa.data_provenance / adjudication)
  • packingGroup· canonical change (coa.data_provenance / adjudication)
  • signalWord· canonical change (coa.data_provenance / adjudication)
  • unNumber· canonical change (coa.data_provenance / adjudication)
canonical_change
1.22026-07-22Canonical data updated: 2 fields changed via the provenance/adjudication pipeline.
  • dotSubsidiaryHazardClass· canonical change (coa.data_provenance / adjudication)
  • dotProperShippingName· canonical change (coa.data_provenance / adjudication)
canonical_change
1.12026-06-18Canonical data re-verified: 7 fields updated against independent vendor SDSs, CLP Annex VI, 49 CFR, and OSHA HazCom 2024 (GHS classification, hazard/precautionary codes, signal word, physical properties as applicable).
  • boilingPoint· canonical adjudication / reground (coa.data_provenance)
  • color· canonical adjudication / reground (coa.data_provenance)
  • countryOfOrigin· canonical adjudication / reground (coa.data_provenance)
  • ghsClassification· canonical adjudication / reground (coa.data_provenance)
  • hsCode· canonical adjudication / reground (coa.data_provenance)
  • refractiveIndex· canonical adjudication / reground (coa.data_provenance)
  • specificGravity· canonical adjudication / reground (coa.data_provenance)
canonical_change
1.02026-05-20Initial URL-first TDS published from canonical chemistry registry.initial

This Technical Data Sheet is provided for technical reference. The Safety Data Sheet (SDS) controls in all cases where guidance differs. Values reflect Alliance Chemical canonical data at time of generation; subsequent revisions are recorded in the Revision History above.

Methyl Ethyl Ketone (MEK) Technical Grade — Technical Data Sheet | Alliance Chemical