Industrial chemicals · Taylor, TX
Technical Data Sheet

Technical Data Sheet

Methyl n-Propyl Ketone (MPK) ACS

ACS Grade · 94%

CAS Number
107-87-9
Alliance Code
methyl-n-propyl-ketone-mpk-acs
Generated
2026-08-31
Revision
1.3
Reviewed
2026-07-17 · Andre Taki
2D chemical structure of Methyl n-Propyl Ketone (MPK) ACS
Structure · PubChem
Last reviewed 2026-07-17 by Andre Taki, DOT Hazmat Specialist.

Identity & Composition

Product Name
Methyl n-Propyl Ketone (MPK) ACS
Alliance Code
methyl-n-propyl-ketone-mpk-acs
Grade
ACS Grade
Concentration
94%
CAS Number
107-87-9PubChem
Formula
C5H10OPubChem
Molecular Weight
86.13PubChem
Product Type
pure_substance

Specifications

TestSpecificationTypicalMethodSource
Assay (Methyl Propyl Ketone)99.50 MIN %99.9 %Gas chromatography (Eastman TCMD-A-AN-G-GC-170)Supplier specification
Acid as Acetic0.0200 MAX %0.0015 %Titration (Eastman TCMD-A-AN-G-VA-12)Supplier specification
Methyl Isobutyl Ketone0.10 MAX %0.01 %Gas chromatography (Eastman TCMD-A-AN-G-GC-170)Supplier specification
Other Ketones0.10 MAX %0.03 %Gas chromatography (Eastman TCMD-A-AN-G-GC-170)Supplier specification
Water0.1000 MAX %0.015 %Karl Fischer (Eastman TCMD-A-AN-G-VA-336)Supplier specification
Residue After Evaporation0.001 wt % max.0.0002 wt %ASTM D1353Interpreted

Specification values are guaranteed limits. Typical values are representative of production lots and are not guaranteed. Lot-specific certificates of analysis ship with every order.

Available GradesSame CAS, alternate grades and concentrations

GradeConcentrationTypical AssaySKUTDS
This grade ACS Grade94%currentcurrent
Reagentmethyl-n-propyl-ketone-mpkView TDS →

Typical assay shown is the rolling-window mean from the sibling product's most recent lots. Grade selection drives downstream end-use — verify the sibling grade matches your specification before substitution.

Physical & Chemical Properties

PropertyValueSource
Appearancecolorless transparent liquidSupplier specification
FormLiquidPublished reference
Color15 MAX pcsSupplier specification
OdorCharacteristic acetone-like odorPublished reference
Specific Gravity (20 °C)0.806 - 0.809Supplier specification
Density0.809 at 68 °F (USCG, 1999) - Less dense than water; will floatPublished reference
Boiling Point101.0 - 104.0 °C (incl. 102.3 °C)Interpreted
Melting Point-108 °F (NTP, 1992)Published reference
Flash Point45 °F (NTP, 1992)Published reference
Vapor Pressure12 mmHg at 68 °F ; 16 mmHg at 77 °F; 21 mmHg at 86 °F (NTP, 1992)Published reference
Solubility (water)10 to 50 mg/mL at 72 °F (NTP, 1992)Published reference
Refractive Index (nD 20)1.3890 - 1.3910 @ 20°CSupplier specification

Regulatory & Transport

DOT / 49 CFR

UN Number
UN124949 CFR 172.101
Hazard Class
3Adjudicated
Packing Group
IIAdjudicated
Proper Shipping Name
Methyl propyl ketoneAdjudicated

GHS / OSHA HazCom 2012

Signal Word
DangerAdjudicated
H-Codes (Hazard Statements)
H225, H302, H319, H335Adjudicated
P-Codes (Precautionary Statements)
P210, P233, P240, P241, P242, P243, P261, P264, P270, P271, P280, P301+P312, P303+P361+P353, P304+P340, P305+P351+P338, P314, P330, P337+P313, P370+P378, P403+P233, P403+P235, P405, P501Adjudicated

Occupational Exposure Limits

OSHA PEL (29 CFR 1910.1000)
no canonical
ACGIH TLV
no canonical
NIOSH REL
no canonical
NIOSH IDLH
no canonical

Transport descriptions reflect 49 CFR 172.101 lookup at time of publication. Sourced data: ECHA CLP Annex VI for harmonised classifications, NIOSH Pocket Guide for REL/IDLH, OSHA Z-Tables for PEL. Always verify against the latest regulatory text before shipment-critical decisions.

Supplier Qualification Packet

One zipped download containing the TDS, SDS, latest lot COA (when available), and a fresh Letter of Continuing Guaranty for Methyl n-Propyl Ketone (MPK) ACS. Every file included is SHA-256 hashed and listed in a manifest your QA team can audit.

Download audit packet

Applications

  • Active solvent for most synthetic resins, including acrylics, polyesters, cellulosics, epoxies, vinyls and alkydsproductcatalog.eastman.com
  • Letdown solvent for high-solids resins used to formulate low-VOC coatingsproductcatalog.eastman.com

Applications are drawn from published manufacturer and supplier documentation; each is sourced. Suitability for a specific use is the buyer's to confirm.

Storage & Handling

Recommended Storage
Cool, dry, well-ventilated area in original sealed containers. Refer to product SDS for material-specific guidance.Class-level guidance — not product-specific; the SDS controls.
Handling Precautions
Use standard chemical PPE — splash goggles, gloves, lab coat. Refer to SDS for hazard-specific PPE requirements.Class-level guidance — not product-specific; the SDS controls.
Incompatibilities
Consult the SDS for material-specific incompatibilities.Class-level guidance — not product-specific; the SDS controls.
Shelf Life
Consult Technical Services for product-specific shelf life

For full hazard, PPE, and emergency response guidance, refer to the Safety Data Sheet (SDS) for this product. The SDS controls in all cases where guidance differs.

Packaging & Logistics

Shipping Description (US DOT)

UN1249, Methyl propyl ketone, 3, PG II

Sourced from 49 CFR 172.101. Confirm against shipping documents and carrier requirements before tender.

NMFC Class
70
Placard
Flammable Liquid
Packing Group
PG II

Revision History

Last reviewed 2026-07-17 by Andre Taki, DOT Hazmat Specialist.

VersionDateChangeTrigger
1.32026-08-05Canonical data updated: 1 field changed via the provenance/adjudication pipeline.
  • unNumber· canonical change (coa.data_provenance / adjudication)
canonical_change
1.22026-07-22Canonical data updated: 3 fields changed via the provenance/adjudication pipeline.
  • dotSubsidiaryHazardClass· canonical change (coa.data_provenance / adjudication)
  • dotProperShippingName· canonical change (coa.data_provenance / adjudication)
  • ghsClassification· canonical change (coa.data_provenance / adjudication)
canonical_change
1.12026-07-17Canonical data re-verified: 5 fields updated against independent vendor SDSs, CLP Annex VI, 49 CFR, and OSHA HazCom 2024 (GHS classification, hazard/precautionary codes, signal word, physical properties as applicable).
  • countryOfOrigin· canonical adjudication / reground (coa.data_provenance)
  • ghsClassification· canonical adjudication / reground (coa.data_provenance)
  • hazard_h_codes· canonical adjudication / reground (coa.data_provenance)
  • hazard_p_codes· canonical adjudication / reground (coa.data_provenance)
  • hsCode· canonical adjudication / reground (coa.data_provenance)
canonical_change
1.02026-05-20Initial URL-first TDS published from canonical chemistry registry.initial

This Technical Data Sheet is provided for technical reference. The Safety Data Sheet (SDS) controls in all cases where guidance differs. Values reflect Alliance Chemical canonical data at time of generation; subsequent revisions are recorded in the Revision History above.