Industrial chemicals · Taylor, TX
Technical Data Sheet

Technical Data Sheet

Phosphoric Acid 5% ACS Grade

ACS · 5%

CAS Number
7664-38-2
Alliance Code
phosphoric-acid-5-acs-grade
Generated
2026-08-31
Revision
1.4
Reviewed
2026-07-17 · Andre Taki
2D chemical structure of Phosphoric Acid 5% ACS Grade
Structure · PubChem
Last reviewed 2026-07-17 by Andre Taki, DOT Hazmat Specialist.

Identity & Composition

Product Name
Phosphoric Acid 5% ACS Grade
Alliance Code
phosphoric-acid-5-acs-grade
Grade
ACS
Concentration
5%
CAS Number
7664-38-2PubChem
Formula
H3O4PPubChem
Molecular Weight
97.995PubChem
Product Type
solution

Specifications

TestSpecificationTypicalMethodSource
Assay (H3PO4)4.5 - 5.5 %5.0 %Commercial practice
Arsenic (As)0.06 ppm Max0.0018 ppmDerived by dilution
Calcium (Ca)0.00012 % Max0.000012 %Derived by dilution
Chloride (Cl)0.18 ppm Max0.024 ppmDerived by dilution
Heavy metals (as Pb)0.00006 % max0.000006 %Derived by dilution
Insoluble matter0.00006 % Max0.00001 %Derived by dilution
Iron (Fe)0.00018 % Max0.000006 %Derived by dilution
Magnesium (Mg)0.00012 % Max0.000006 %Derived by dilution
Nitrate (NO3)0.29 ppm Max0.029 ppmDerived by dilution
Sodium (Na)0.0015 % Max0.00012 %Derived by dilution
Sulfate (SO4)0.00018 % Max0.000029 %Derived by dilution
Substances reducing permanganate (as H3PO3)0.00006 % Max0.000012 %ACS permanganate titrationInterpreted

Specification values are guaranteed limits. Typical values are representative of production lots and are not guaranteed. Lot-specific certificates of analysis ship with every order.

Available GradesSame CAS, alternate grades and concentrations

GradeConcentrationTypical AssaySKUTDS
This grade ACS5%currentcurrent
75%phosphoric-acid-75View TDS →
USP Food Grade75%phosphoric-acid-75-usp-food-gradeView TDS →
ACS50%phosphoric-acid-50-acs-gradeView TDS →
Technical50%phosphoric-acid-50-technical-gradeView TDS →
ACS30%phosphoric-acid-30-acs-gradeView TDS →
Food20%phosphoric-acid-20-food-gradeView TDS →
Technical20%phosphoric-acid-20-technical-gradeView TDS →
Technical10%phosphoric-acid-10-technical-gradeView TDS →
Food5%phosphoric-acid-5-food-gradeView TDS →
Technical5%phosphoric-acid-5-technical-gradeView TDS →
Foodphosphoric-acid-45-food-gradeView TDS →
Technicalphosphoric-acid-45-technical-gradeView TDS →

Typical assay shown is the rolling-window mean from the sibling product's most recent lots. Grade selection drives downstream end-use — verify the sibling grade matches your specification before substitution.

Physical & Chemical Properties

PropertyValueSource
Color10 maxDerived by dilution
Specific Gravity (20 °C)1.022 - 1.028Interpreted

Strong acid — density and vapor-pressure values shown are at 20 °C; values shift markedly with concentration and temperature. Reference concentration-temperature curves before specifying equipment.

Materials of ConstructionService envelope ≈ 5%

MaterialRatingMax T (°C)NotesSource
Buna-N (NBR)
elastomer
PoorHardens and cracks; do not use.Parker O-ring Chemical Compatibility
EPDM
elastomer
Good80Standard for HCl and H2SO4 gaskets.Parker O-ring Chemical Compatibility
Viton (FKM)
elastomer
Good80Acceptable for HCl gaskets up to 37 %.Parker O-ring Chemical Compatibility
PTFE
fluoropolymer
Excellent200Universal acid compatibility.Cole-Parmer Chemical Compatibility
PVDF (Kynar)
fluoropolymer
Excellent120Excellent for HCl piping at elevated temperature.Cole-Parmer Chemical Compatibility
Borosilicate Glass
glass ceramic
Excellent100Inert to most strong acids (avoid HF).Cole-Parmer Chemical Compatibility
Glass (borosilicate)
glass ceramic
Excellent100Inert under all conditionsCole-Parmer Chemical Compatibility
316 stainless steel
metal
Poor25Severe pitting; use only for vaporsCole-Parmer Chemical Compatibility
Aluminium
metal
Not recommendedReacts to form H2 gasCole-Parmer Chemical Compatibility
Carbon Steel
metal
Not recommendedCatastrophic corrosion; never use.Cole-Parmer Chemical Compatibility
Hastelloy C-276
metal
Excellent80Preferred metal for concentrated HCl service.Haynes International C-276 datasheet
Inconel 625
metal
Good60Acceptable for dilute serviceCole-Parmer Chemical Compatibility
Tantalum
metal
Excellent100Best-in-class but expensiveCole-Parmer Chemical Compatibility
CPVC
thermoplastic
Excellent90Higher-temp variant of PVC.Cole-Parmer Chemical Compatibility
FRP (vinyl ester)
thermoplastic
Good60Common bulk-storage tank materialCole-Parmer Chemical Compatibility
HDPE
thermoplastic
Excellent60Standard tank/drum material for HCl up to 37 %.Cole-Parmer Chemical Compatibility
PVC
thermoplastic
Excellent60Common for piping; verify rating for service > 50 °C.Cole-Parmer Chemical Compatibility

Ratings reflect the service envelope (concentration × temperature) shown. Always confirm against your specific duty cycle and contact-time before equipment selection. The most cautious rating across overlapping references is shown.

Materials Selection Tool

Showing 17 of 17 materials compatible at the selected envelope.

MaterialRatingMax T (°C)Notes
Buna-N (NBR)
elastomer
PoorHardens and cracks; do not use.
EPDM
elastomer
Good80Standard for HCl and H2SO4 gaskets.
Viton (FKM)
elastomer
Good80Acceptable for HCl gaskets up to 37 %.
PTFE
fluoropolymer
Excellent200Universal acid compatibility.
PVDF (Kynar)
fluoropolymer
Excellent120Excellent for HCl piping at elevated temperature.
Borosilicate Glass
glass ceramic
Excellent100Inert to most strong acids (avoid HF).
Glass (borosilicate)
glass ceramic
Excellent100Inert under all conditions
316 stainless steel
metal
Poor25Severe pitting; use only for vapors
Aluminium
metal
Not recommendedReacts to form H2 gas
Carbon Steel
metal
Not recommendedCatastrophic corrosion; never use.
Hastelloy C-276
metal
Excellent80Preferred metal for concentrated HCl service.
Inconel 625
metal
Good60Acceptable for dilute service
Tantalum
metal
Excellent100Best-in-class but expensive
CPVC
thermoplastic
Excellent90Higher-temp variant of PVC.
FRP (vinyl ester)
thermoplastic
Good60Common bulk-storage tank material
HDPE
thermoplastic
Excellent60Standard tank/drum material for HCl up to 37 %.
PVC
thermoplastic
Excellent60Common for piping; verify rating for service > 50 °C.

Regulatory & Transport

DOT / 49 CFR

UN Number
UN1805Adjudicated
Hazard Class
8Adjudicated
Packing Group
IIIAdjudicated
Proper Shipping Name
Phosphoric acid solutionAdjudicated

GHS / OSHA HazCom 2012

Signal Word
DangerAdjudicated
H-Codes (Hazard Statements)
H314Adjudicated
P-Codes (Precautionary Statements)
P234, P260, P264, P280, P301+P330+P331, P303+P361+P353, P304+P340, P305+P351+P338, P310, P321, P363, P405, P501Adjudicated

Occupational Exposure Limits

OSHA PEL (29 CFR 1910.1000)
1 mg/m³ TWAOSHA 29 CFR 1910.1000
ACGIH TLV
no canonical
NIOSH REL
1 mg/m³ TWA / 3 mg/m³ STELNIOSH Pocket Guide
NIOSH IDLH
1000 mg/m³NIOSH Pocket Guide

Transport descriptions reflect 49 CFR 172.101 lookup at time of publication. Sourced data: ECHA CLP Annex VI for harmonised classifications, NIOSH Pocket Guide for REL/IDLH, OSHA Z-Tables for PEL. Always verify against the latest regulatory text before shipment-critical decisions.

Supplier Qualification Packet

One zipped download containing the TDS, SDS, latest lot COA (when available), and a fresh Letter of Continuing Guaranty for Phosphoric Acid 5% ACS Grade. Every file included is SHA-256 hashed and listed in a manifest your QA team can audit.

Download audit packet

Catalog EquivalentsCross-reference vs major chemical suppliers

Sigma-Aldrich

SKUGradeConc.MatchNotes
345245ACS Reagent85%ExactACS Reagent ≥85%

Cross-references are informational. Confirm against the manufacturer's current specification before substitution. Competitor trademarks are property of their respective owners.

Applications

  • Fertilizer manufacture, and use as a pH modifier, sanitizing agent and rust converterlaballey.com
  • Supplied for laboratory, research or manufacturing use as ACS reagent-grade materialdigitalassets.avantorsciences.com
  • Used in fertilizer, cosmetics, foods and beverages, food-industry sanitation, dental cleaning, and rust conversion.laballey.com

Applications are drawn from published manufacturer and supplier documentation; each is sourced. Suitability for a specific use is the buyer's to confirm.

Storage & Handling

Recommended Storage
Cool, dry, well-ventilated area in compatible containers (lined steel, HDPE, FRP — verify per concentration). Segregate from bases, oxidizers, metals, and cyanides.Class-level guidance — not product-specific; the SDS controls.
Handling Precautions
Use full PPE including face shield, acid-resistant gloves and apron. Add acid to water slowly with stirring; never reverse. Ventilation required.Class-level guidance — not product-specific; the SDS controls.
Incompatibilities
Bases, active metals (aluminium, zinc), cyanides, sulfides, oxidizing agents. Reacts violently with organic anhydrides.Class-level guidance — not product-specific; the SDS controls.
Shelf Life
Consult Technical Services for product-specific shelf life

For full hazard, PPE, and emergency response guidance, refer to the Safety Data Sheet (SDS) for this product. The SDS controls in all cases where guidance differs.

Packaging & Logistics

Shipping Description (US DOT)

UN1805, Phosphoric acid solution, 8, PG III

Sourced from 49 CFR 172.101. Confirm against shipping documents and carrier requirements before tender.

NMFC Class
65
Placard
Corrosive
Packing Group
PG III

Revision History

Last reviewed 2026-07-17 by Andre Taki, DOT Hazmat Specialist.

VersionDateChangeTrigger
1.42026-08-19Canonical data updated: 1 field changed via the provenance/adjudication pipeline.
  • unNumber· canonical change (coa.data_provenance / adjudication)
canonical_change
1.32026-08-05Canonical data updated: 3 fields changed via the provenance/adjudication pipeline.
  • hazardClass· canonical change (coa.data_provenance / adjudication)
  • packingGroup· canonical change (coa.data_provenance / adjudication)
  • unNumber· canonical change (coa.data_provenance / adjudication)
canonical_change
1.22026-07-22Canonical data updated: 2 fields changed via the provenance/adjudication pipeline.
  • dotSubsidiaryHazardClass· canonical change (coa.data_provenance / adjudication)
  • dotProperShippingName· canonical change (coa.data_provenance / adjudication)
canonical_change
1.12026-07-17Canonical data re-verified: 6 fields updated against independent vendor SDSs, CLP Annex VI, 49 CFR, and OSHA HazCom 2024 (GHS classification, hazard/precautionary codes, signal word, physical properties as applicable).
  • countryOfOrigin· canonical adjudication / reground (coa.data_provenance)
  • ghsClassification· canonical adjudication / reground (coa.data_provenance)
  • hazard_h_codes· canonical adjudication / reground (coa.data_provenance)
  • hazard_p_codes· canonical adjudication / reground (coa.data_provenance)
  • hsCode· canonical adjudication / reground (coa.data_provenance)
  • signalWord· canonical adjudication / reground (coa.data_provenance)
canonical_change
1.02026-05-20Initial URL-first TDS published from canonical chemistry registry.initial

This Technical Data Sheet is provided for technical reference. The Safety Data Sheet (SDS) controls in all cases where guidance differs. Values reflect Alliance Chemical canonical data at time of generation; subsequent revisions are recorded in the Revision History above.