Industrial chemicals · Taylor, TX
Technical Data Sheet

Technical Data Sheet

Potassium Hydroxide 45% Solution Technical Grade

Technical · 45%

Alliance Code
potassium-hydroxide-45-solution-technical-grade-caustic-potash-liquid-koh
Reviewed
2026-08-27
Revision
1.2
CAS number
1310-58-3
UN number
UN1814
Hazard class · packing group
8 · PG II
Structure
2D chemical structure of Potassium Hydroxide 45% Solution Technical Grade
Structure · PubChem
Grade
Technical · 45%
Signal word
Danger
Hazards
CorrosiveIrritant / harmfulH290 H302 H314
Proper shipping name
Potassium hydroxide solution
Last reviewed 2026-08-27.

Identity & Composition

Product Name
Potassium Hydroxide 45% Solution Technical Grade
Alliance Code
potassium-hydroxide-45-solution-technical-grade-caustic-potash-liquid-koh
Grade
Technical
Concentration
45%
CAS Number
1310-58-3Adjudicated
Formula
HKOAdjudicated
Molecular Weight
56.106Adjudicated
Product Type
solution

Specifications

TestSpecificationTypicalMethodSource
Chloride (as Cl), ppm75 Max.8.6 ppm—Interpreted
Heavy metals (as Pb)5 ppm max.0.5 ppm—Interpreted
KCl30 ppm max.18 ppm—Interpreted
KOH43-47%45 %—Interpreted
Mercury (as Hg), ppm0.1 Max.0.005 ppm—Interpreted
Nickel as Ni (ppm by wt.)0.25 max0.10 ppm—Interpreted
Potassium carbonate (as K2CO3), %0.2 Max.0.06 %—Interpreted
Potassium chlorate as KClO3 (ppm by wt.)30 max6 ppm—Interpreted
Sodium2500 ppm max.1200 ppm—Interpreted
Potassium sulfate as K2SO4 (ppm by wt.)10 max3 ppm—Interpreted
Iron (Fe)0.5 ppm max.0.25 ppmEPA-6010BInterpreted

Values are reproduced from the current product reference. Source labels do not by themselves establish a supplier guarantee or a test result for your lot. Confirm applicable acceptance limits and request lot-specific documentation.

Available GradesSame CAS, alternate grades and concentrations

GradeConcentrationTypical AssaySKUTDS
This grade Technical45%—currentcurrent
ACS Reagent45%—potassium-hydroxide-45-solution-acs-gradeView TDS →
Technical30%—potassium-hydroxide-30-solution-technical-gradeView TDS →
Technical25%—potassium-hydroxide-25-solution-technical-grade-caustic-potash-liquid-kohView TDS →

Typical assay shown is the rolling-window mean from the sibling product's most recent lots. Grade selection drives downstream end-use — verify the sibling grade matches your specification before substitution.

Physical & Chemical Properties

PropertyValueSource
ColorWater WhiteInterpreted
Specific Gravity (20 °C)1.4531Interpreted

Strong base — hygroscopic; values may drift in opened containers. See storage guidance.

Materials of Construction

MaterialRatingConditionsSource
HDPECompatible45% (w/w) KOH aqueous solution, technical grade; basis is the supplier packaging the 45% solution in an HDPE bottlemedia.vwr.com

Compatibility is drawn from published manufacturer and supplier documentation for this product; each rating is sourced. Confirm against your specific duty cycle before equipment selection.

Materials Selection Tool

Showing 14 of 14 material ratings within the selected envelope.

MaterialRatingMax T (°C)Notes
Buna-N (NBR)
elastomer
Fair40Limited service life
EPDM
elastomer
Excellent100Standard for caustic gaskets.
Viton (FKM)
elastomer
Poor—Hydrolyzes in caustic; do not use.
PTFE
fluoropolymer
Excellent200Universal compatibility.
304 stainless steel
metal
Good80Acceptable for dilute caustic
316L Stainless Steel
metal
Excellent80Preferred metal for caustic service.
Aluminium
metal
Not recommended—Rapid attack; generates hydrogen
Carbon Steel
metal
Good60Acceptable below 70 °C; caustic embrittlement risk above.
Nickel
metal
Excellent100Preferred for high-temperature caustic
Zinc / galvanized steel
metal
Not recommended—Rapid corrosion
HDPE
thermoplastic
Excellent60Standard tote/drum material.
Polypropylene
thermoplastic
Excellent80Excellent caustic service to 50 %.
PP
thermoplastic
Excellent80Preferred for elevated temperature
PVC
thermoplastic
Good40Acceptable for ambient service

Regulatory & Transport

DOT / 49 CFR

UN Number
UN1814Adjudicated
Hazard Class
8Adjudicated
Packing Group
IIAdjudicated
Proper Shipping Name
Potassium hydroxide solutionAdjudicated

GHS / OSHA HazCom 2012

Signal Word
DangerAdjudicated
H-Codes (Hazard Statements)
H290, H302, H314Adjudicated
P-Codes (Precautionary Statements)
P234, P260, P264, P270, P280, P301+P312+P330, P301+P330+P331, P303+P361+P353, P304+P340, P305+P351+P338, P310, P321, P363, P405, P501Adjudicated

Occupational Exposure Limits

OSHA PEL (29 CFR 1910.1000)
—no canonical
ACGIH TLV
—no canonical
NIOSH REL
2 mg/m³ ceilingNIOSH Pocket Guide
NIOSH IDLH
—no canonical

Transport descriptions reflect 49 CFR 172.101 lookup at time of publication. Sourced data: ECHA CLP Annex VI for harmonised classifications, NIOSH Pocket Guide for REL/IDLH, OSHA Z-Tables for PEL. Always verify against the latest regulatory text before shipment-critical decisions.

Supplier Qualification Packet

One zipped download containing the TDS, SDS, latest lot COA (when available), and a fresh Letter of Continuing Guaranty for Potassium Hydroxide 45% Solution Technical Grade. Every file included is SHA-256 hashed and listed in a manifest your QA team can audit.

Download audit packet

Applications

  • Industrial uses of potassium hydroxide: detergents/soaps, dyeing and bleaching, paint and varnish removers, electroplating, photo engraving, lithography, alkaline batteries, analytical chemistry, fuel and gas, thickening agent, organic synthesis, stabilizercorecheminc.com
  • Used in a large number of manufacturing processesstore.astm.org

Applications are drawn from published manufacturer and supplier documentation; each is sourced. Suitability for a specific use is the buyer's to confirm.

Storage & Handling

Recommended Storage
Cool, dry, well-ventilated area in compatible containers (HDPE, lined steel — not aluminium). Tightly sealed; protect from atmospheric moisture and CO2. Segregate from acids and oxidizers.Class-level guidance — not product-specific; the SDS controls.
Handling Precautions
Use full PPE including chemical splash goggles and alkali-resistant gloves. Add base to water slowly with stirring. Highly exothermic dilution.Class-level guidance — not product-specific; the SDS controls.
Incompatibilities
Acids (violent neutralization), aluminium, zinc, tin (generates hydrogen gas), halogens, organic nitro compounds.Class-level guidance — not product-specific; the SDS controls.
Shelf Life
24 monthsmedia.vwr.comNot stated in the source beyond the product being the 45% (w/w) technical grade solution

For full hazard, PPE, and emergency response guidance, refer to the Safety Data Sheet (SDS) for this product. The SDS controls in all cases where guidance differs.

Packaging & Logistics

Shipping Description (US DOT)

UN1814, Potassium hydroxide solution, 8, PG II

Sourced from 49 CFR 172.101. Confirm against shipping documents and carrier requirements before tender.

NMFC Class
60
Placard
Corrosive
Packing Group
PG II

Revision History

VersionDateChangeTrigger
1.22026-08-27Canonical data updated: 1 field changed via the provenance/adjudication pipeline.
  • oel_niosh_rel· canonical change (coa.data_provenance / adjudication)
canonical_change
1.12026-08-11Canonical data updated: 12 fields changed via the provenance/adjudication pipeline.
  • casNumber· canonical change (coa.data_provenance / adjudication)
  • formula· canonical change (coa.data_provenance / adjudication)
  • molecularWeight· canonical change (coa.data_provenance / adjudication)
  • unNumber· canonical change (coa.data_provenance / adjudication)
  • hazardClass· canonical change (coa.data_provenance / adjudication)
  • packingGroup· canonical change (coa.data_provenance / adjudication)
  • dotProperShippingName· canonical change (coa.data_provenance / adjudication)
  • signalWord· canonical change (coa.data_provenance / adjudication)
  • ghsClassification· canonical change (coa.data_provenance / adjudication)
  • hazard_h_codes· canonical change (coa.data_provenance / adjudication)
  • hazard_p_codes· canonical change (coa.data_provenance / adjudication)
  • dotSubsidiaryHazardClass· canonical change (coa.data_provenance / adjudication)
canonical_change

This Technical Data Sheet is provided for technical reference. The Safety Data Sheet (SDS) controls in all cases where guidance differs. Values reflect Alliance Chemical canonical data at time of generation; subsequent revisions are recorded in the Revision History above.