Industrial chemicals · Taylor, TX
Technical Data Sheet

Technical Data Sheet

Potassium Hydroxide (KOH) Technical Grade

Technical · 90.3%

Alliance Code
potassium-hydroxide-flakes-koh
Reviewed
2026-06-18
Revision
1.6
CAS number
1310-58-3
UN number
UN1813
Hazard class · packing group
8 · PG II
Structure
2D chemical structure of Potassium Hydroxide (KOH) Technical Grade
Structure · PubChem
Grade
Technical · 90.3%
Signal word
Danger
Hazards
CorrosiveIrritant / harmfulH290 H302 H314
Proper shipping name
Potassium Hydroxide, solid
Last reviewed 2026-06-18 by Andre Taki, Chief Commercial Officer.

Identity & Composition

Product Name
Potassium Hydroxide (KOH) Technical Grade
Alliance Code
potassium-hydroxide-flakes-koh
Grade
Technical
Concentration
90.3%
CAS Number
1310-58-3PubChem
Formula
—PubChem
Molecular Weight
—PubChem
Product Type
Pure substance

Specifications

TestSpecificationTypicalMethodSource
Hydroxide alkalinity as KOH (wt. %)90 min91.0 wt %—Interpreted
Arsenic (As)0.0003 %0.000011 %—Interpreted
Potassium chloride as KCl (ppm by wt.)150 max39 ppm—Interpreted
Heavy metals (as Pb)≤0.002%0.00009 %—Interpreted
Iron as Fe (ppm by wt.)3 max1.1 ppm—Interpreted
Lead (Pb)0.005 %0.000011 %—Interpreted
Nickel as Ni (ppm by wt.)4 max1.4 ppm—Interpreted
Potassium Carbonate (K2CO3)≤1.0%0.40 %—Interpreted
Sulfate (SO4)0.05%0.00044 %—Interpreted
Insoluble matter in H2O0.05 %0.0009 %—Interpreted
Sodium (as Na)0.5% Max.0.30 %Flame AAS / ICP-OESInterpreted

Values are reproduced from the current product reference. Source labels do not by themselves establish a supplier guarantee or a test result for your lot. Confirm applicable acceptance limits and request lot-specific documentation.

Physical & Chemical Properties

PropertyValueSource
AppearanceWhite crystalline powderAdjudicated
FormSolidPublished reference
OdorOdorlessAdjudicated
pH13.5–14 (0.1 M to 10% solution)Adjudicated
Specific Gravity2.04 (water = 1)Adjudicated
Density1.45 to 1.50 at 68 °F (USCG, 1999)Published reference
Boiling Point1,320–1,327 °C (2,408–2,421 °F)Adjudicated
Melting Point360–406 °C (680–763 °F), depending on water contentAdjudicated
Flash PointNot applicableAdjudicated
Vapor PressureNegligible at 20 °C (1 mmHg at 719 °C)Adjudicated
Solubility (water)Very soluble in water, about 1,120–1,210 g/L at 20–25 °C (strongly exothermic); soluble in alcohol and glycerinAdjudicated

Strong base — hygroscopic; values may drift in opened containers. See storage guidance.

Materials of ConstructionService envelope ≈ 90.3%

MaterialRatingMax T (°C)NotesSource
Buna-N (NBR)
elastomer
Fair40Limited service lifeCole-Parmer Chemical Compatibility
EPDM
elastomer
Excellent90Preferred elastomerCole-Parmer Chemical Compatibility
Viton (FKM)
elastomer
Poor—Not recommended above 25%Cole-Parmer Chemical Compatibility
PTFE
fluoropolymer
Excellent200Universal compatibility.Cole-Parmer Chemical Compatibility
304 stainless steel
metal
Good80Acceptable for dilute causticCole-Parmer Chemical Compatibility
316 stainless steel
metal
Excellent95Standard caustic serviceCole-Parmer Chemical Compatibility
Aluminium
metal
Not recommended—Rapid attack; generates hydrogenCole-Parmer Chemical Compatibility
Carbon steel
metal
Good50Acceptable to 50 °C; caustic embrittlement aboveCole-Parmer Chemical Compatibility
Nickel
metal
Excellent100Preferred for high-temperature causticCole-Parmer Chemical Compatibility
Zinc / galvanized steel
metal
Not recommended—Rapid corrosionCole-Parmer Chemical Compatibility
HDPE
thermoplastic
Excellent60Standard drum / IBC materialCole-Parmer Chemical Compatibility
PP
thermoplastic
Excellent80Preferred for elevated temperatureCole-Parmer Chemical Compatibility
PVC
thermoplastic
Good40Acceptable for ambient serviceCole-Parmer Chemical Compatibility

Ratings reflect the service envelope (concentration × temperature) shown. Always confirm against your specific duty cycle and contact-time before equipment selection. The most cautious rating across overlapping references is shown.

Materials Selection Tool

Showing 13 of 13 material ratings within the selected envelope.

MaterialRatingMax T (°C)Notes
Buna-N (NBR)
elastomer
Fair40Limited service life
EPDM
elastomer
Excellent90Preferred elastomer
Viton (FKM)
elastomer
Poor—Not recommended above 25%
PTFE
fluoropolymer
Excellent200Universal compatibility.
304 stainless steel
metal
Good80Acceptable for dilute caustic
316 stainless steel
metal
Excellent95Standard caustic service
Aluminium
metal
Not recommended—Rapid attack; generates hydrogen
Carbon steel
metal
Good50Acceptable to 50 °C; caustic embrittlement above
Nickel
metal
Excellent100Preferred for high-temperature caustic
Zinc / galvanized steel
metal
Not recommended—Rapid corrosion
HDPE
thermoplastic
Excellent60Standard drum / IBC material
PP
thermoplastic
Excellent80Preferred for elevated temperature
PVC
thermoplastic
Good40Acceptable for ambient service

Regulatory & Transport

DOT / 49 CFR

UN Number
UN181349 CFR 172.101
Hazard Class
8Adjudicated
Packing Group
IIAdjudicated
Proper Shipping Name
Potassium Hydroxide, solidAdjudicated

GHS / OSHA HCS 2024

Signal Word
DangerAdjudicated
H-Codes (Hazard Statements)
H290, H302, H314Adjudicated
P-Codes (Precautionary Statements)
P234, P260, P264, P270, P280, P301+P312+P330, P301+P330+P331, P303+P361+P353, P304+P340, P305+P351+P338, P310, P321, P363, P390, P405, P406, P501Adjudicated

Occupational Exposure Limits

OSHA PEL (29 CFR 1910.1000)
—no canonical
ACGIH TLV
2 mg/m³ CeilingAdjudicated
NIOSH REL
2 mg/m³ CeilingAdjudicated
NIOSH IDLH
—no canonical

Transport descriptions reflect 49 CFR 172.101 lookup at time of publication. Sourced data: NIOSH Pocket Guide for REL/IDLH, OSHA Z-Tables for PEL. Always verify against the latest regulatory text before shipment-critical decisions.

Health & Fire Hazard

Acute Toxicology

LD₅₀ Oral (rat)
214–333 mg/kg (rat), the basis for H302Adjudicated

Acute toxicology values from SDS Section 11 or NIOSH RTECS.

Supplier Qualification Packet

One zipped download containing the TDS, SDS, latest lot COA (when available), and a fresh Letter of Continuing Guaranty for Potassium Hydroxide (KOH) Technical Grade. Every file included is SHA-256 hashed and listed in a manifest your QA team can audit.

Download audit packet

Applications

  • Industrial uses of potassium hydroxide: detergents/soaps, dyeing and bleaching, paint and varnish removers, electroplating, photo engraving, lithography, alkaline batteries, analytical chemistry, fuel and gas, thickening agent, organic synthesis, stabilizercorecheminc.com
  • Used in a large number of manufacturing processesstore.astm.org

Applications are drawn from published manufacturer and supplier documentation; each is sourced. Suitability for a specific use is the buyer's to confirm.

Storage & Handling

Recommended Storage
Keep tightly closed in a dry place — the flakes absorb moisture and carbon dioxide from air. Use steel, polyethylene or polypropylene containers, never aluminum or galvanized metal. Keep away from acids.Adjudicated
Handling Precautions
Use full PPE including chemical splash goggles and alkali-resistant gloves. Add base to water slowly with stirring. Highly exothermic dilution.Class-level guidance — not product-specific; the SDS controls.
Incompatibilities
Water in quantity (violent heat release); acids (violent reaction); aluminum, zinc, tin, copper, magnesium and their alloys (release flammable hydrogen); nitro compounds; organic materials; halogenated compounds.Adjudicated
Shelf Life
Consult Technical Services for product-specific shelf life

For full hazard, PPE, and emergency response guidance, refer to the Safety Data Sheet (SDS) for this product. The SDS controls in all cases where guidance differs.

Packaging & Logistics

Shipping Description (US DOT)

UN1813, Potassium Hydroxide, solid, 8, PG II

Sourced from 49 CFR 172.101. Confirm against shipping documents and carrier requirements before tender.

NMFC Class
60
Placard
Corrosive
Packing Group
PG II

Revision History

Last reviewed 2026-06-18 by Andre Taki, Chief Commercial Officer, DOT Hazmat–certified (49 CFR 172.704).

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1.62026-10-08Canonical data updated: 20 fields changed via the provenance/adjudication pipeline.
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1.52026-10-07Canonical data updated: 3 fields changed via the provenance/adjudication pipeline.
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1.42026-09-30Canonical data updated: 3 fields changed via the provenance/adjudication pipeline.
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1.22026-07-22Canonical data updated: 1 field changed via the provenance/adjudication pipeline.
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1.12026-06-18Canonical data re-verified: 3 fields updated against independent vendor SDSs, CLP Annex VI, 49 CFR, and OSHA HazCom 2024 (GHS classification, hazard/precautionary codes, signal word, physical properties as applicable).
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1.02026-05-20Initial URL-first TDS published from canonical chemistry registry.initial

This Technical Data Sheet is provided for technical reference. The Safety Data Sheet (SDS) controls in all cases where guidance differs. Values reflect Alliance Chemical canonical data at time of generation; subsequent revisions are recorded in the Revision History above.