Industrial chemicals · Taylor, TX
Technical Data Sheet

Technical Data Sheet

Sodium Metabisulfite - Food Grade

Food Grade

Alliance Code
sodium-metabisulfite-food-grade
Reviewed
2026-07-17
Revision
1.5
CAS number
7681-57-4
Structure
2D chemical structure of Sodium Metabisulfite - Food Grade
Structure · PubChem
Grade
Food Grade
Signal word
Danger
Hazards
CorrosiveIrritant / harmfulH302 H318
Last reviewed 2026-07-17 by Andre Taki, Chief Commercial Officer.

Identity & Composition

Product Name
Sodium Metabisulfite - Food Grade
Alliance Code
sodium-metabisulfite-food-grade
Grade
Food Grade
Concentration
—
CAS Number
7681-57-4PubChem
Formula
—PubChem
Molecular Weight
—PubChem
Product Type
Pure substance

Specifications

TestSpecificationTypicalMethodSource
Assay (Na2S2O5)Not less than 90.0% and not more than 100.5% of Na2S2O595.12 %—Interpreted
Arsenic (As)0.0 – 1.0 ppm0.11 ppm—Interpreted
Heavy metals (as Pb)0.0 – 10.0 ppm0.52 ppm—Interpreted
IdentificationA 1:10 aqueous solution gives positive tests for Sodium and for SulfitePasses test—Interpreted
Insoluble matter< 0.005 wt. %0.0017 %—Interpreted
Lead (Pb)Not more than 2 mg/kg0.16 mg/kg—Interpreted
Screen size, through 20 mesh (U.S. Sieve), % by weight92 - 100 %96.4 %—Interpreted
Selenium< 5.0 ppm0.12 ppm—Interpreted
Chloride (Cl)0.0 – 0.02 %0.0069 %—Interpreted
Iron (Fe)Not more than 10 mg/kg2.3 mg/kg—Interpreted
Sodium thiosulfate (Na2S2O3)0.0 – 0.04 %0.0072 %—Interpreted
Sodium sulfite (Na2SO3)0.0 – 0.6 %0.19 %—Interpreted
Mercury (Hg)Not more than 1 mg/kg0.017 mg/kgCold vapour AAS (FCC Mercury Limit Test / AOAC 971.21)Interpreted
Sulfur dioxide (SO2), availableMin. 65.0%66.1%Iodometric titration (FCC assay procedure)Interpreted
on no. 4010 - 50 %26.3 %—Interpreted
through no. 1000 - 15 %7.2 %—Interpreted

Values are reproduced from the current product reference. Source labels do not by themselves establish a supplier guarantee or a test result for your lot. Confirm applicable acceptance limits and request lot-specific documentation.

Available GradesSame CAS, alternate grades and concentrations

GradeConcentrationTypical AssaySKUTDS
This grade Food Grade——currentcurrent
ACS Grade——sodium-metabisulfite-acs-gradeView TDS →
Technical Grade——sodium-metabisulfite-technical-gradeView TDS →

Typical assay shown is the rolling-window mean from the sibling product's most recent lots. Grade selection drives downstream end-use — verify the sibling grade matches your specification before substitution.

Physical & Chemical Properties

One or more physical-property values are temporarily suppressed pending verification against vendor COA data. For complete properties refer to the Safety Data Sheet (SDS) or contact sales@alliancechemical.com.

PropertyValueSource
AppearanceColorless crystals or a white to yellow, crystalline powderInterpreted
OdorIn the presences of traces of water, it develops an odor of sulfur dioxidePublished reference
pH4.0-4.8Interpreted
Density1.4 (NIOSH, 2024) - Denser than water; will sinkPublished reference
Boiling PointDecomposes (NIOSH, 2024)Published reference
Melting Pointgreater than 302 °F (Decomposes) (NIOSH, 2024)Adjudicated

Materials of Construction

MaterialRatingConditionsSource
polyethylene (sealed bags)Compatibledry granular solid as supplied in manufacturer's standard packaging; no concentration or temperature statedessecousa.com
polypropylene (bulk sacks)Compatibledry granular solid as supplied in manufacturer's standard packaging; no concentration or temperature statedessecousa.com

Compatibility is drawn from published manufacturer and supplier documentation for this product; each rating is sourced. Confirm against your specific duty cycle before equipment selection.

Regulatory & Transport

DOT / 49 CFR

UN Number
Not regulatedAdjudicated
Hazard Class
Not regulatedAdjudicated
Packing Group
Not regulatedAdjudicated
Proper Shipping Name
Not regulatedAdjudicated

GHS / OSHA HCS 2024

Signal Word
DangerAdjudicated
H-Codes (Hazard Statements)
H302, H318Adjudicated
P-Codes (Precautionary Statements)
P264, P270, P280, P301+P312, P305+P351+P338, P310, P313, P330, P501Adjudicated

Occupational Exposure Limits

OSHA PEL (29 CFR 1910.1000)
—no canonical
ACGIH TLV
—no canonical
NIOSH REL
5 mg/m³ TWANIOSH Pocket Guide
NIOSH IDLH
—no canonical

Transport descriptions reflect 49 CFR 172.101 lookup at time of publication. Sourced data: NIOSH Pocket Guide for REL/IDLH, OSHA Z-Tables for PEL. Always verify against the latest regulatory text before shipment-critical decisions.

Supplier Qualification Packet

One zipped download containing the TDS, SDS, latest lot COA (when available), and a fresh Letter of Continuing Guaranty for Sodium Metabisulfite - Food Grade. Every file included is SHA-256 hashed and listed in a manifest your QA team can audit.

Download audit packet

Applications

  • Additive, preservative, antioxidant, anti-microbial agent and leavening agent in the food industryessecousa.com
  • Preservative in food applications, cherry brining, dechlorination in municipal wastewater / pulp & paper / textile water treatment, oxygen scavenging, and gold miningineos.com
  • FCC food-grade function: preservative and antioxidantmubychem.com
  • Reducing agent for chemical manufacturing, preservative, water treatment and photographic auxiliary, bleaching agent, and ensiling agent (FCC 97%+ material)wintersunchemical.com
  • Oxygen scavenging in steam boiler water treatment and removal of excess chlorine from wastewateressecousa.com
  • Reducing and sulfonating agent in chemical processing, including surfactants and polymerizationessecousa.com
  • Preservation of silage in feed applications.essecousa.com
  • Used as a preservative excipient in the pharmaceutical industry.essecousa.com
  • Component of photographic developer baths and stabilizing agent for fixers.essecousa.com

Applications are drawn from published manufacturer and supplier documentation; each is sourced. Suitability for a specific use is the buyer's to confirm.

Storage & Handling

Recommended Storage
Keep containers tightly closed in a cool, dry, well-ventilated place away from heat, moisture, water, acids and oxidizing agents; it releases sulfur dioxide slowly in humid air. The product consumes oxygen, so oxygen deficiency can develop in closed containers and tanks.Adjudicated
Handling Precautions
Use standard chemical PPE — splash goggles, gloves, lab coat. Refer to SDS for hazard-specific PPE requirements.Class-level guidance — not product-specific; the SDS controls.
Incompatibilities
Acids (release toxic sulfur dioxide gas); water and ice; strong oxidizing agents; nitrites and nitrates; chlorates; alkalis and strong bases; heavy-metal compounds.Adjudicated
Shelf Life
36 monthsessecousa.comproperly stored in original packaging, in a controlled indoor environment that is cool, dry and well ventilated

For full hazard, PPE, and emergency response guidance, refer to the Safety Data Sheet (SDS) for this product. The SDS controls in all cases where guidance differs.

Packaging & Logistics

Shipping Description (US DOT)

Not regulated for transport.

Confirm against shipping documents and carrier requirements before tender.

NMFC Class
70

Revision History

Last reviewed 2026-07-17 by Andre Taki, Chief Commercial Officer, DOT Hazmat–certified (49 CFR 172.704).

VersionDateChangeTrigger
1.52026-10-13Canonical data updated: 4 fields changed via the provenance/adjudication pipeline.
  • storage_precautions· canonical change (coa.data_provenance / adjudication)
  • incompatible_materials· canonical change (coa.data_provenance / adjudication)
  • conditions_to_avoid· canonical change (coa.data_provenance / adjudication)
  • hazardous_decomposition_products· canonical change (coa.data_provenance / adjudication)
canonical_change
1.42026-10-07Canonical data updated: 3 fields changed via the provenance/adjudication pipeline.
  • ghsClassification· canonical change (coa.data_provenance / adjudication)
  • hazard_h_codes· canonical change (coa.data_provenance / adjudication)
  • hazard_p_codes· canonical change (coa.data_provenance / adjudication)
canonical_change
1.32026-10-05Canonical data updated: 1 field changed via the provenance/adjudication pipeline.
  • oel_niosh_rel· canonical change (coa.data_provenance / adjudication)
canonical_change
1.22026-09-30Canonical data updated: 1 field changed via the provenance/adjudication pipeline.
  • meltingPoint· canonical change (coa.data_provenance / adjudication)
canonical_change
1.12026-07-17Canonical data re-verified: 7 fields updated against independent vendor SDSs, CLP Annex VI, 49 CFR, and OSHA HazCom 2024 (GHS classification, hazard/precautionary codes, signal word, physical properties as applicable).
  • countryOfOrigin· canonical adjudication / reground (coa.data_provenance)
  • dotSubsidiaryHazardClass· canonical adjudication / reground (coa.data_provenance)
  • ghsClassification· canonical adjudication / reground (coa.data_provenance)
  • hazard_h_codes· canonical adjudication / reground (coa.data_provenance)
  • hazard_p_codes· canonical adjudication / reground (coa.data_provenance)
  • hsCode· canonical adjudication / reground (coa.data_provenance)
  • physicalProperties· canonical adjudication / reground (coa.data_provenance)
canonical_change
1.02026-05-20Initial URL-first TDS published from canonical chemistry registry.initial

This Technical Data Sheet is provided for technical reference. The Safety Data Sheet (SDS) controls in all cases where guidance differs. Values reflect Alliance Chemical canonical data at time of generation; subsequent revisions are recorded in the Revision History above.