Industrial chemicals · Taylor, TX
Technical Data Sheet

Technical Data Sheet

Methyl n-Propyl Ketone (MPK) Technical Grade

Technical

Alliance Code
methyl-n-propyl-ketone-mpk
確認日
2026-07-17
Revision
1.6
CAS番号
107-87-9
UN番号
UN1249
危険有害性クラス・容器等級
3 · PG II
構造
2D chemical structure of Methyl n-Propyl Ketone (MPK) Technical Grade
構造・PubChem
グレード
Technical
注意喚起語
Danger
危険有害性
引火性刺激性 / 有害性健康有害性H225 H302 H319 H335 H351
正式輸送品名
Methyl propyl ketone
Last reviewed 2026-07-17 by Andre Taki, Chief Commercial Officer.

Identity & Composition

製品名
Methyl n-Propyl Ketone (MPK) Technical Grade
Alliance Code
methyl-n-propyl-ketone-mpk
グレード
Technical
濃度
—
CAS番号
107-87-9PubChem
化学式
—PubChem
分子量
86.13PubChem
製品種別
Pure substance

Specifications

TestSpecificationTypicalMethodSource
Assay (Methyl Propyl Ketone)90.00 MIN %97.6 %Gas chromatographyInterpreted
Acid as Acetic0.0100 MAX %0.0031 %TitrationInterpreted
Acidity (as Acetic Acid)0.01 wt % max.0.0031 wt %—Interpreted
Color (Pt-Co)15 max.9—Interpreted
Methyl Isobutyl Ketone10.00 MAX %2.0 %Gas chromatographyInterpreted
Water0.0500 MAX %0.022 %—Interpreted
Distillation Range @ 760 mmHg100 - 117 °C108.2 °CASTM D1078Interpreted
Nonvolatile Matter0.005 g/100 mL max.0.00045 g/100 mLASTM D1353Interpreted

Values are reproduced from the current product reference. Source labels do not by themselves establish a supplier guarantee or a test result for your lot. Confirm applicable acceptance limits and request lot-specific documentation.

Available GradesSame CAS, alternate grades and concentrations

グレード濃度Typical AssaySKUTDS
This grade Technical——currentcurrent
ACS Grade94%—methyl-n-propyl-ketone-mpk-acsView TDS →

Typical assay shown is the rolling-window mean from the sibling product's most recent lots. Grade selection drives downstream end-use — verify the sibling grade matches your specification before substitution.

物理的及び化学的性質

Property値Source
外観Colorless, volatile liquid with a sweet, fruity odorAdjudicated
形状LiquidPublished reference
臭いSweet, acetone-like ketone odorAdjudicated
比重0.81 at 20–25 °C (water = 1)Adjudicated
密度0.809 at 68 °F (USCG, 1999) - Less dense than water; will floatPublished reference
沸点100–105 °C (212–221 °F)Adjudicated
融点-78 °C (-108 °F)Adjudicated
引火点7 °C (45 °F), closed cupAdjudicated
蒸気圧27 mmHg (36 hPa) at 20 °CAdjudicated
Solubility (water)Slightly soluble in water (about 43 g/L at 20 °C); miscible with most organic solventsAdjudicated
Refractive Index (nD 20)1.387 - 1.393Interpreted
粘度0.5 mPa·s at 20 °CAdjudicated

Polar solvent — purity vs. intended end-use (electronics, pharma, general industrial) is the dominant grade consideration. See application guidance for grade selection.

Materials of ConstructionService envelope ≈ 100%

MaterialRatingMax T (°C)NotesSource
Buna-N (NBR)
elastomer
Fair60Acceptable for alcohols; poor for ketones.Parker O-ring Chemical Compatibility
EPDM
elastomer
Fair—Good for alcohols, poor for estersCole-Parmer Chemical Compatibility
Viton (FKM)
elastomer
Fair80Swells in acetone and esters; avoid for those.Parker O-ring Chemical Compatibility
FFKM (Kalrez)
fluoropolymer
Excellent200Premium ester / ketone sealingCole-Parmer Chemical Compatibility
PTFE
fluoropolymer
Excellent200Universal solvent compatibility.Cole-Parmer Chemical Compatibility
Borosilicate Glass
glass ceramic
Excellent100Universally inert.Cole-Parmer Chemical Compatibility
316L Stainless Steel
metal
Excellent80Inert; preferred for high-purity solvent service.Cole-Parmer Chemical Compatibility
Aluminium
metal
Good40Acceptable; avoid prolonged wet contactCole-Parmer Chemical Compatibility
Carbon Steel
metal
Fair50Trace moisture causes rust; flash-rust prevention required.Cole-Parmer Chemical Compatibility
HDPE
thermoplastic
Fair40Swells with many polar solvents; verify per solvent.Cole-Parmer Chemical Compatibility
PP
thermoplastic
Good50Acceptable but watch swelling with estersCole-Parmer Chemical Compatibility
PVC
thermoplastic
Fair25Esters soften PVC; avoid for estersCole-Parmer Chemical Compatibility

Ratings reflect the service envelope (concentration × temperature) shown. Always confirm against your specific duty cycle and contact-time before equipment selection. The most cautious rating across overlapping references is shown.

Materials Selection Tool

Showing 12 of 12 material ratings within the selected envelope.

MaterialRatingMax T (°C)Notes
Buna-N (NBR)
elastomer
Fair60Acceptable for alcohols; poor for ketones.
EPDM
elastomer
Fair—Good for alcohols, poor for esters
Viton (FKM)
elastomer
Fair80Swells in acetone and esters; avoid for those.
FFKM (Kalrez)
fluoropolymer
Excellent200Premium ester / ketone sealing
PTFE
fluoropolymer
Excellent200Universal solvent compatibility.
Borosilicate Glass
glass ceramic
Excellent100Universally inert.
316L Stainless Steel
metal
Excellent80Inert; preferred for high-purity solvent service.
Aluminium
metal
Good40Acceptable; avoid prolonged wet contact
Carbon Steel
metal
Fair50Trace moisture causes rust; flash-rust prevention required.
HDPE
thermoplastic
Fair40Swells with many polar solvents; verify per solvent.
PP
thermoplastic
Good50Acceptable but watch swelling with esters
PVC
thermoplastic
Fair25Esters soften PVC; avoid for esters

Regulatory & Transport

DOT / 49 CFR

国連番号
UN124949 CFR 172.101
危険有害性クラス
3Adjudicated
容器等級
IIAdjudicated
正式輸送品名
Methyl propyl ketoneAdjudicated

GHS / OSHA HCS 2024

注意喚起語
DangerAdjudicated
H-Codes (Hazard Statements)
H225, H302, H319, H335, H351Adjudicated
P-Codes (Precautionary Statements)
P201, P202, P210, P233, P240, P241, P242, P243, P261, P264, P270, P271, P280, P301+P312, P303+P361+P353, P304+P340, P305+P351+P338, P308+P313, P312, P330, P337+P313, P370+P378, P403+P233, P403+P235, P405, P501Adjudicated

許容濃度

OSHA PEL (29 CFR 1910.1000)
200 ppm TWAOSHA 29 CFR 1910.1000
ACGIH TLV
150 ppm STELAdjudicated
NIOSH REL
150 ppm (530 mg/m³) TWAAdjudicated
NIOSH IDLH
1,500 ppmAdjudicated

輸送情報は発行時点の49 CFR 172.101の照会結果を反映しています。データ出典:REL/IDLHはNIOSH Pocket Guide、PELはOSHA Zテーブル。出荷に関わる重要な判断の前に、必ず最新の規制本文で確認してください。

Health & Fire Hazard

Acute Toxicology

LD₅₀ Oral (rat)
1,600 mg/kg (rat), the basis for H302Adjudicated
LD₅₀ Dermal (rabbit)
6,500 mg/kgAdjudicated
LC₅₀ Inhalation (rat, 4 h)
> 25.5 mg/L (vapor, rat, 4 h)Adjudicated

急性毒性値はSDS第11項またはNIOSH RTECSによる。

Supplier Qualification Packet

One zipped download containing the TDS, SDS, latest lot COA (when available), and a fresh Letter of Continuing Guaranty for Methyl n-Propyl Ketone (MPK) Technical Grade. Every file included is SHA-256 hashed and listed in a manifest your QA team can audit.

Download audit packet

Applications

  • Active solvent for most synthetic resins, including acrylics, polyesters, cellulosics, epoxies, vinyls and alkydsproductcatalog.eastman.com
  • Letdown solvent for high-solids resins used to formulate low-VOC coatingsproductcatalog.eastman.com
  • Gravure printing inks, and cleaning and surface preparation for the transportation industryproductcatalog.eastman.com
  • Non-HAP solvent alternative to MEK and toluene for aerospace cleaning and pre-treatmentproductcatalog.eastman.com
  • Medium-evaporating urethane-grade solventproductcatalog.eastman.com
  • Permitted as an inert ingredient in nonfood-use pesticide products under FIFRAproductcatalog.eastman.com
  • Used for cleaning and surface preparation in the transportation industry.productcatalog.eastman.com

Applications are drawn from published manufacturer and supplier documentation; each is sourced. Suitability for a specific use is the buyer's to confirm.

Storage & Handling

Recommended Storage
着火源、酸化剤及び塩基から離し、換気の良い涼しい可燃物保管場所で容器を密閉して保管すること。容器を接地・アースすること。Adjudicated
Handling Precautions
Use chemical-resistant gloves and splash goggles. Bond and ground during transfer to prevent static accumulation. Eliminate ignition sources within vapor envelope.Class-level guidance — not product-specific; the SDS controls.
Incompatibilities
強酸化剤および過酸化物;強塩基;還元剤;アミン類;イソシアネート類。Adjudicated
Shelf Life
Consult Technical Services for product-specific shelf life

For full hazard, PPE, and emergency response guidance, refer to the Safety Data Sheet (SDS) for this product. The SDS controls in all cases where guidance differs.

Packaging & Logistics

Shipping Description (US DOT)

UN1249, Methyl propyl ketone, 3, PG II

Sourced from 49 CFR 172.101. Confirm against shipping documents and carrier requirements before tender.

NMFC Class
70
Placard
Flammable Liquid
容器等級
PG II

Revision History

Last reviewed 2026-07-17 by Andre Taki, Chief Commercial Officer, DOT Hazmat–certified (49 CFR 172.704).

VersionDateChangeTrigger
1.62026-10-08Canonical data updated: 6 fields changed via the provenance/adjudication pipeline.
  • ghsClassification· canonical change (coa.data_provenance / adjudication)
  • hazard_h_codes· canonical change (coa.data_provenance / adjudication)
  • hazard_p_codes· canonical change (coa.data_provenance / adjudication)
  • rcra_waste_codes· canonical change (coa.data_provenance / adjudication)
  • cercla_rq· canonical change (coa.data_provenance / adjudication)
  • restrictions_on_use· canonical change (coa.data_provenance / adjudication)
canonical_change
1.52026-10-07Canonical data updated: 27 fields changed via the provenance/adjudication pipeline.
  • ghsClassification· canonical change (coa.data_provenance / adjudication)
  • hazard_h_codes· canonical change (coa.data_provenance / adjudication)
  • hazard_p_codes· canonical change (coa.data_provenance / adjudication)
  • synonyms· canonical change (coa.data_provenance / adjudication)
  • restrictions_on_use· canonical change (coa.data_provenance / adjudication)
  • odor· canonical change (coa.data_provenance / adjudication)
  • flashPoint· canonical change (coa.data_provenance / adjudication)
  • boilingPoint· canonical change (coa.data_provenance / adjudication)
  • meltingPoint· canonical change (coa.data_provenance / adjudication)
  • vaporPressure· canonical change (coa.data_provenance / adjudication)
  • specificGravity· canonical change (coa.data_provenance / adjudication)
  • solubility· canonical change (coa.data_provenance / adjudication)
  • viscosity· canonical change (coa.data_provenance / adjudication)
  • autoIgnitionTemperature· canonical change (coa.data_provenance / adjudication)
  • explosiveLimits· canonical change (coa.data_provenance / adjudication)
  • partitionCoefficient· canonical change (coa.data_provenance / adjudication)
  • oel_acgih_tlv· canonical change (coa.data_provenance / adjudication)
  • oel_niosh_rel· canonical change (coa.data_provenance / adjudication)
  • oel_idlh· canonical change (coa.data_provenance / adjudication)
  • incompatible_materials· canonical change (coa.data_provenance / adjudication)
  • conditions_to_avoid· canonical change (coa.data_provenance / adjudication)
  • hazardous_decomposition_products· canonical change (coa.data_provenance / adjudication)
  • storage_precautions· canonical change (coa.data_provenance / adjudication)
  • rcra_waste_codes· canonical change (coa.data_provenance / adjudication)
  • cercla_rq· canonical change (coa.data_provenance / adjudication)
  • dot_transport_note· canonical change (coa.data_provenance / adjudication)
  • recommended_use· canonical change (coa.data_provenance / adjudication)
canonical_change
1.42026-10-05Canonical data updated: 3 fields changed via the provenance/adjudication pipeline.
  • oel_niosh_rel· canonical change (coa.data_provenance / adjudication)
  • oel_idlh· canonical change (coa.data_provenance / adjudication)
  • oel_osha_pel· canonical change (coa.data_provenance / adjudication)
canonical_change
1.32026-09-30Canonical data updated: 4 fields changed via the provenance/adjudication pipeline.
  • boilingPoint· canonical change (coa.data_provenance / adjudication)
  • meltingPoint· canonical change (coa.data_provenance / adjudication)
  • flashPoint· canonical change (coa.data_provenance / adjudication)
  • appearance· canonical change (coa.data_provenance / adjudication)
canonical_change
1.22026-07-22Canonical data updated: 2 fields changed via the provenance/adjudication pipeline.
  • dotSubsidiaryHazardClass· canonical change (coa.data_provenance / adjudication)
  • ghsClassification· canonical change (coa.data_provenance / adjudication)
canonical_change
1.12026-07-17Canonical data re-verified: 5 fields updated against independent vendor SDSs, CLP Annex VI, 49 CFR, and OSHA HazCom 2024 (GHS classification, hazard/precautionary codes, signal word, physical properties as applicable).
  • countryOfOrigin· canonical adjudication / reground (coa.data_provenance)
  • ghsClassification· canonical adjudication / reground (coa.data_provenance)
  • hazard_h_codes· canonical adjudication / reground (coa.data_provenance)
  • hazard_p_codes· canonical adjudication / reground (coa.data_provenance)
  • hsCode· canonical adjudication / reground (coa.data_provenance)
canonical_change
1.02026-05-20Initial URL-first TDS published from canonical chemistry registry.initial

This Technical Data Sheet is provided for technical reference. The Safety Data Sheet (SDS) controls in all cases where guidance differs. Values reflect Alliance Chemical canonical data at time of generation; subsequent revisions are recorded in the Revision History above.