Industrial chemicals · Taylor, TX
Safety Data Sheet

Safety Data Sheet · GHS Rev. 9

Trichloroethylene (TCE) Technical Grade

Technical Grade

CAS Number
79-01-6
GHS Revision
Rev. 9 (2021)
Generated
Emergency
Chemtel 1-800-255-3924 (24/7)
Download Full SDS PDF

The downloadable PDF is the signed, archival SDS. This page mirrors its content across all 16 GHS sections.

Last reviewed 2026-05-20.
2D chemical structure of Trichloroethylene (TCE) Technical Grade
Structure · PubChem

SDS · Answer summary

Trichloroethylene (TCE) Technical Grade is regulated for transport under DOT 49 CFR — see the shipping classification below.

UN Number
UN1710
DOT Hazard Class
6.1
Packing Group
III
Proper Shipping Name
TRICHLOROETHYLENE
GHS Signal Word
Danger
GHS Hazards
H315, H317, H319, H336, H341, H350, H412
Section 1

Identification

Product Identifier
Trichloroethylene (TCE) Technical Grade
Grade
Technical Grade
CAS Number
79-01-6
Chemical Formula
C2HCl3
Molecular Weight
131.38 g/mol
Manufacturer
Alliance Chemical
204 South Edmond Street, Taylor, TX 76574
Emergency Phone
Chemtel 1-800-255-3924 (24/7)
Recommended Use
Industrial / laboratory chemical. See Section 7.
Section 2

Hazard Identification

GHS pictogram: Irritant / harmful
Irritant / harmful
GHS pictogram: Health hazard
Health hazard
Signal Word
Danger
Hazard Statements
  • H315Causes skin irritation
  • H317May cause an allergic skin reaction
  • H319Causes serious eye irritation
  • H336May cause drowsiness or dizziness
  • H341Suspected of causing genetic defects
  • H350May cause cancer
  • H412Harmful to aquatic life with long lasting effects
Precautionary Statements
  • P201Obtain special instructions before use.
  • P202Do not handle until all safety precautions have been read and understood.
  • P261Avoid breathing dust, fume, gas, mist, vapours or spray.
  • P264Wash hands and face thoroughly after handling.
  • P271Use only outdoors or in a well-ventilated area.
  • P272Contaminated work clothing should not be allowed out of the workplace.
  • P273Avoid release to the environment.
  • P280Wear protective gloves, protective clothing, and eye/face protection.
  • P281Use personal protective equipment as required.
  • P302+P352IF ON SKIN: Wash with plenty of water and soap.
  • P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
  • P308+P313IF exposed or concerned: Get medical advice or attention.
  • P312Call a POISON CENTER or doctor if you feel unwell.
  • P321Specific treatment (see first-aid information on this label).
  • P332+P313If skin irritation occurs: Get medical advice or attention.
  • P333+P313If skin irritation or rash occurs: Get medical advice or attention.
  • P337+P313If eye irritation persists: Get medical advice or attention.
  • P362Take off contaminated clothing and wash before reuse.
  • P391Collect spillage.
  • P403+P233Store in a well-ventilated place. Keep container tightly closed.
  • P405Store locked up.
  • P501Dispose of contents and container in accordance with local, regional, national, and international regulations.

Hazard (H) and precautionary (P) statements and pictograms conform to GHS Rev. 9. The full classification rationale is in the downloadable SDS PDF.

Section 3

Composition / Information on Ingredients

Composition and information on ingredients
ComponentCAS No.FormulaConcentration
Trichloroethylene79-01-6C2HCl3>=99.5000 (w/w)

Concentrations are nominal; lot-specific values appear on the Certificate of Analysis. Components not contributing to classification are omitted.

Section 4

First-Aid Measures

Eyes
Rinse with plenty of water for at least 15 minutes. Remove contact lenses if present and easy to do. Continue rinsing. Seek medical attention immediately.
Skin
Immediately flush with plenty of water for at least 15 minutes while removing contaminated clothing. Wash with soap. Get medical attention immediately.
Inhalation
Move person to fresh air and keep comfortable for breathing. If breathing is difficult, give oxygen. If not breathing, give artificial respiration. Get medical attention immediately.
Ingestion
Do Not Induce Vomiting! Never give anything by mouth to an unconscious person. If conscious, wash out mouth with water. Get medical attention immediately.
Section 5

Fire-Fighting Measures

Suitable Extinguishing Media
Use water spray, alcohol-resistant foam, dry chemical, or CO2. Use measures appropriate to local circumstances.
Unsuitable Extinguishing Media
Do not use a solid water stream as it may scatter and spread fire.
Protective Equipment
Wear self-contained breathing apparatus and full protective clothing.
Hazardous Combustion Products
May include carbon oxides and other toxic fumes. See Section 10.
Section 6

Accidental Release Measures

Personal Precautions
Use PPE as described in Section 8. Ensure adequate ventilation. Evacuate personnel to safe areas.
Environmental Precautions
Prevent leakage or spillage from entering drains, sewers, or waterways.
Containment & Cleanup
Absorb with inert material. Collect in appropriate waste container. Dispose per applicable regulations.
Section 7

Handling and Storage

Safe Handling
Use with adequate ventilation. Avoid contact with skin, eyes, and clothing. Wash thoroughly after handling. Keep container closed when not in use.
Safe Storage
Store in a cool, dry, well-ventilated area. Keep away from incompatible materials (see Section 10). Keep containers tightly closed.
Section 8

Exposure Controls / Personal Protection

Occupational Exposure Limits

Occupational exposure limits
LimitValue
OSHA PEL100 ppm TWA / 200 ppm acceptable ceiling / 300 ppm 5-min peak
NIOSH RELCa (carcinogen — minimize occupational exposure)
IDLH1000 ppm
Engineering Controls
Use adequate ventilation. Provide eyewash stations and quick-drench showers accessible to areas of use.
Eye/Face Protection
Wear chemical safety goggles or face shield.
Skin Protection
Wear chemical-resistant gloves and protective clothing.
Respiratory Protection
Use a NIOSH-approved air-purifying respirator with cartridges appropriate for the contaminant. For higher exposures or confined spaces, use supplied-air or a powered air-purifying respirator (PAPR).

Exposure limits sourced from NIOSH Pocket Guide and OSHA 29 CFR 1910.1000. Hazard classification from ECHA Classification and Labelling Inventory (CLP Annex VI).

Section 9

Physical & Chemical Properties

Form
Liquid
Odor
Ethereal odor
Density
1.46 at 68 °F (USCG, 1999) - Denser than water; will sink g/cm³
Boiling Point
189 °F at 760 mmHg (NTP, 1992) °C
Melting Point
-99 °F (NTP, 1992) °C
Flash Point
greater than 200 °F (NTP, 1992) °C
Vapor Pressure
60 mmHg at 68 °F ; 77 mmHg at 77 °F (NTP, 1992) mmHg
Solubility
less than 1 mg/mL at 70 °F (NTP, 1992)

Values shown reflect product-specific canonical data. Lot-specific ranges may vary; see the Certificate of Analysis for the shipped lot.

Section 10

Stability and Reactivity

Chemical Stability
Stable under recommended storage conditions.
Possibility of Hazardous Reactions
None under normal processing conditions.
Conditions to Avoid
Heat, sparks, open flame, and incompatible materials.
Incompatible Materials
Strong oxidizing agents, strong acids, strong bases.
Hazardous Decomposition Products
May produce carbon oxides and other toxic fumes when heated to decomposition.
Section 11

Toxicological Information

See Section 2 for GHS hazard classification.

Carcinogen Classification

Carcinogen classification
AgencyStatus
IARCClassified as a carcinogen — see Section 2 (H350: May cause cancer).
NTPNot listed as carcinogen.
OSHANot listed as carcinogen.
Section 12

Ecological Information

Aquatic Hazard
  • H412Harmful to aquatic life with long lasting effects
Ecotoxicity
Daphnia EC50: 2 mg/L (96 h, Palaemonetes paludosus (grass shrimp; crustacean, not Daphnia)); Fish LC50: 20 mg/L (96 h, Cyprinodon variegatus (sheepshead minnow))
Persistence & Degradability
Persists in groundwater (anaerobic dechlorination half-life 0.14–3.3 yr) — NOT readily biodegradable (2.4% ThOD in 2 wk, MITI)
Bioaccumulative Potential
BCF 4–39 (bluegill 17, carp 4–17, rainbow trout 39)
Mobility in Soil
High mobility (Koc ~101); volatile
Section 13

Disposal Considerations

Dispose of contents/container in accordance with applicable federal, state, and local regulations. Do not dispose of into drains or waterways.

Section 14

Transport Information

US DOT (49 CFR)

UN Number
UN1710
Proper Shipping Name
TRICHLOROETHYLENE
Hazard Class
6.1
Packing Group
III

IMDG / IATA classifications may differ. Refer to the downloadable SDS PDF for international transport details. Verify current regulations before international shipment.

Section 15

Regulatory Information

Regulatory inventory listings
Inventory / ListStatus
California Proposition 65Listed (since 1988-04-01)
US EPA TSCA Active InventoryListed
EPCRA SARA 313 (TRI)Listed

SARA 311/312 hazard categories correspond to the GHS classification in Section 2. Data retrieved as of: California Proposition 65 2026-05-05; US EPA TSCA Active Inventory 2026-05-05; EPCRA SARA 313 (TRI) 2026-05-05.

Section 16

Other Information

Revision Date
GHS Format
GHS Rev. 9 (2021), 16-section format per OSHA HCS 2024 (29 CFR 1910.1200).

Disclaimer: The information provided in this Safety Data Sheet is correct to the best of our knowledge at the date of publication. It relates only to the specific product identified and does not relate to its use in combination with other materials. ALLIANCE CHEMICAL MAKES NO WARRANTY, EXPRESS OR IMPLIED, INCLUDING WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE. ALLIANCE CHEMICAL DOES NOT ASSUME LIABILITY FOR LOSS, INJURY, DAMAGE, OR EXPENSE ARISING FROM THE HANDLING, STORAGE, USE, OR DISPOSAL OF THIS PRODUCT.

Alliance Chemical, 204 South Edmond Street, Taylor, TX 76574. Published by Alliance Chemical from first-party canonical product data. Our authority is hands-on chemical handling, DOT/GHS-compliant shipping, and government-registered distribution — not bench chemistry. This summary reflects canonical regulatory data on file; refer to the full SDS PDF for the complete regulatory record.