Industrial chemicals · Taylor, TX
Technical Data Sheet

Technical Data Sheet

Citric Acid Anhydrous - Food Grade

Food

CAS Number
77-92-9
Alliance Code
citric-acid-anhydrous-food-grade
Generated
2026-08-31
Revision
1.1
Reviewed
2026-07-17 · Andre Taki
2D chemical structure of Citric Acid Anhydrous - Food Grade
Structure · PubChem
Last reviewed 2026-07-17 by Andre Taki, DOT Hazmat Specialist.

Identity & Composition

Product Name
Citric Acid Anhydrous - Food Grade
Alliance Code
citric-acid-anhydrous-food-grade
Grade
Food
Concentration
CAS Number
77-92-9PubChem
Formula
C6H8O7PubChem
Molecular Weight
192.12PubChem
Product Type

Specifications

TestSpecificationTypicalMethodSource
Assay (anhydrous basis)Not less than 99.5% and not more than 100.5%100.0 %Titration (FCC/USP citric acid assay)FCC
Arsenic<= 1.00 ppm0.05 ppmArsenic - TN20560Supplier specification
Heavy Metals (as lead)Maximum 5.0 ppm0.3 ppmHeavy Metals as Lead - TN20630Supplier specification
IdentificationMeets USP/FCCPasses testSupplier specification
LeadNot more than 0.5 mg/kg0.05 mg/kgLead by AA - TN20680FCC
Limit of Oxalic Acid<= 100.00 ppm15 ppmOxalate - TN20740Supplier specification
Oxalate100 mg/kg15 mg/kgFCC
Residue on Ignition (sulfated ash)Not more than 0.05%0.008 %Sulfated Ash - TN20910FCC
Readily Carbonizable SubstancesNot darker than matching fluid K.Passes testReadily Carbonizable Substances - TN20875Supplier specification
SulfateMaximum 0.015%0.003 %Sulfate - TN20905Supplier specification
Tridodecylamine0.1 mg/kg0.01 mg/kgFCC
Tridodecylamine (solvent-extracted material only)<= 100.0 ppb10 ppbTridodecylamine - TN20880Supplier specification
WaterNot more than 0.5%0.2 %Karl Fischer (Moisture - TN20700 per Tate & Lyle sheet)FCC
aluminium0.2 mg/kg max0.02 mg/kgSupplier specification
bacterial endotoxins0.5 I.U./MG max0.05Supplier specification
calcium100 mg/kg max10 mg/kgSupplier specification
chloride50 mg/kg max3 mg/kgSupplier specification
chromium1 mg/kg max0.05 mg/kgSupplier specification
cobalt1 mg/kg max0.01 mg/kgSupplier specification
iron5 mg/kg max0.3 mg/kgSupplier specification
mercury0.5 mg/kg max0.005 mg/kgSupplier specification
nickel1 mg/kg max0.1 mg/kgSupplier specification

Specification values are guaranteed limits. Typical values are representative of production lots and are not guaranteed. Lot-specific certificates of analysis ship with every order.

Available GradesSame CAS, alternate grades and concentrations

GradeConcentrationTypical AssaySKUTDS
This grade Foodcurrentcurrent
Reagent50%citric-acid-50-solutionView TDS →
Technical25%citric-acid-25-solutionView TDS →
ACS Reagentcitric-acid-anhydrous-acs-reagent-gradeView TDS →

Typical assay shown is the rolling-window mean from the sibling product's most recent lots. Grade selection drives downstream end-use — verify the sibling grade matches your specification before substitution.

Physical & Chemical Properties

PropertyValueSource
AppearanceFree-flowing, colorless, translucent crystals or as a white granular to fine crystalline powder.Supplier specification
OdorOdorlessPublished reference
Density1.54 at 68 °F (USCG, 1999) - Denser than water; will sinkPublished reference
Boiling PointDecomposes (NTP, 1992)Published reference
Melting Point307 °F (anhydrous) (NTP, 1992)Published reference
Flash Point100 °CPublished reference
Solubility (water)greater than or equal to 100 mg/mL at 72 °F (NTP, 1992)Published reference

Regulatory & Transport

DOT / 49 CFR

UN Number
Not regulatedAdjudicated
Hazard Class
Not regulatedAdjudicated
Packing Group
Not regulatedAdjudicated
Proper Shipping Name
Not regulatedAdjudicated

GHS / OSHA HazCom 2012

Signal Word
WarningAdjudicated
H-Codes (Hazard Statements)
H319, H335Adjudicated
P-Codes (Precautionary Statements)
P261, P264, P271, P280, P304+P340, P305+P351+P338, P314, P337+P313, P403+P233, P405, P501Adjudicated

Occupational Exposure Limits

OSHA PEL (29 CFR 1910.1000)
no canonical
ACGIH TLV
no canonical
NIOSH REL
no canonical
NIOSH IDLH
no canonical

Transport descriptions reflect 49 CFR 172.101 lookup at time of publication. Sourced data: ECHA CLP Annex VI for harmonised classifications, NIOSH Pocket Guide for REL/IDLH, OSHA Z-Tables for PEL. Always verify against the latest regulatory text before shipment-critical decisions.

Supplier Qualification Packet

One zipped download containing the TDS, SDS, latest lot COA (when available), and a fresh Letter of Continuing Guaranty for Citric Acid Anhydrous - Food Grade. Every file included is SHA-256 hashed and listed in a manifest your QA team can audit.

Download audit packet

Applications

  • Acidulant and sequestrant of metal ions in food, beverage and pharmaceutical products, imparting a clean tartness and protecting against off-flavorsingredi.com
  • FCC food-grade functions: sequestrant, dispersing agent, acidifier and flavoring agentmubychem.com
  • Industrial use in the manufacture of ecologically compatible detergents, chemical cleaning, concrete admixtures and plasticizersingredi.com
  • Used as a hydraulic fracturing / well stimulation chemical in oil and shale gas productionmubychem.com
  • Used as an acidulant.ingredi.com
  • Used to sequester metal ions and protect certain foods from off-flavors and off-odors.ingredi.com
  • Used in chemical cleaning, concrete admixtures, and plasticizers.ingredi.com

Applications are drawn from published manufacturer and supplier documentation; each is sourced. Suitability for a specific use is the buyer's to confirm.

Storage & Handling

Recommended Storage
Storage below 75°F and 55% relative humidity in tightly sealed container is recommended.ingredi.com
Handling Precautions
Use standard chemical PPE — splash goggles, gloves, lab coat. Refer to SDS for hazard-specific PPE requirements.Class-level guidance — not product-specific; the SDS controls.
Incompatibilities
Consult the SDS for material-specific incompatibilities.Class-level guidance — not product-specific; the SDS controls.
Shelf Life
36 monthsingredi.comStored below 75°F and 55% relative humidity in a tightly sealed container; retest after 3 years

For full hazard, PPE, and emergency response guidance, refer to the Safety Data Sheet (SDS) for this product. The SDS controls in all cases where guidance differs.

Packaging & Logistics

Shipping Description (US DOT)

Not regulated for transport.

Confirm against shipping documents and carrier requirements before tender.

NMFC Class
70

Revision History

Last reviewed 2026-07-17 by Andre Taki, DOT Hazmat Specialist.

VersionDateChangeTrigger
1.12026-07-17Canonical data re-verified: 10 fields updated against independent vendor SDSs, CLP Annex VI, 49 CFR, and OSHA HazCom 2024 (GHS classification, hazard/precautionary codes, signal word, physical properties as applicable).
  • countryOfOrigin· canonical adjudication / reground (coa.data_provenance)
  • dotProperShippingName· canonical adjudication / reground (coa.data_provenance)
  • dotSubsidiaryHazardClass· canonical adjudication / reground (coa.data_provenance)
  • ghsClassification· canonical adjudication / reground (coa.data_provenance)
  • hazard_h_codes· canonical adjudication / reground (coa.data_provenance)
  • hazard_p_codes· canonical adjudication / reground (coa.data_provenance)
  • hsCode· canonical adjudication / reground (coa.data_provenance)
  • packingGroup· canonical adjudication / reground (coa.data_provenance)
  • physicalProperties· canonical adjudication / reground (coa.data_provenance)
  • unNumber· canonical adjudication / reground (coa.data_provenance)
canonical_change
1.02026-05-20Initial URL-first TDS published from canonical chemistry registry.initial

This Technical Data Sheet is provided for technical reference. The Safety Data Sheet (SDS) controls in all cases where guidance differs. Values reflect Alliance Chemical canonical data at time of generation; subsequent revisions are recorded in the Revision History above.