Industrial chemicals · Taylor, TX
Technical Data Sheet

Technical Data Sheet

Citric Acid Anhydrous - ACS Reagent Grade

ACS Reagent

CAS Number
77-92-9
Alliance Code
citric-acid-anhydrous-acs-reagent-grade
Generated
2026-08-31
Revision
1.1
Reviewed
2026-07-17 · Andre Taki
2D chemical structure of Citric Acid Anhydrous - ACS Reagent Grade
Structure · PubChem
Last reviewed 2026-07-17 by Andre Taki, DOT Hazmat Specialist.

Identity & Composition

Product Name
Citric Acid Anhydrous - ACS Reagent Grade
Alliance Code
citric-acid-anhydrous-acs-reagent-grade
Grade
ACS Reagent
Concentration
CAS Number
77-92-9PubChem
Formula
C6H8O7PubChem
Molecular Weight
192.12PubChem
Product Type

Specifications

TestSpecificationTypicalMethodSource
AssayMin 99.5%99.9%Supplier specification
ChlorideMax 0.001%0.0002%Supplier specification
DescriptionFine granularPasses testACS Reagent Chemicals
IdentificationTo Pass TestPasses testACS Reagent Chemicals
Insoluble MatterMax 0.005%0.005%Supplier specification
IronMax 3 ppm0.2 ppmSupplier specification
LeadMax 2 ppm0.02 ppmSupplier specification
Oxalate (C2O4)To Pass TestPasses testACS Reagent Chemicals
PhosphateMax 0.001%0.0001%Supplier specification
Residue after ignitionMax 0.02%0.003%Supplier specification
Substances carbonizable by hot sulfuric acidPasses testPasses testACS Reagent Chemicals
SulfateMax 0.002%0.0005%Supplier specification
Water (Karl Fischer)Max 0.5%0.1%Karl Fischer titrationSupplier specification
arsenic1 ppm max0.02 ppmSupplier specification
residue0.02 % max0.003%Supplier specification

Specification values are guaranteed limits. Typical values are representative of production lots and are not guaranteed. Lot-specific certificates of analysis ship with every order.

Available GradesSame CAS, alternate grades and concentrations

GradeConcentrationTypical AssaySKUTDS
This grade ACS Reagentcurrentcurrent
Reagent50%citric-acid-50-solutionView TDS →
Technical25%citric-acid-25-solutionView TDS →
Foodcitric-acid-anhydrous-food-gradeView TDS →

Typical assay shown is the rolling-window mean from the sibling product's most recent lots. Grade selection drives downstream end-use — verify the sibling grade matches your specification before substitution.

Physical & Chemical Properties

PropertyValueSource
AppearanceCitric acid appears as colorless, odorless crystals with an acid taste. Denser than water. (USCG, 1999)Published reference
OdorOdorlessPublished reference
Density1.54 at 68 °F (USCG, 1999) - Denser than water; will sinkPublished reference
Boiling PointDecomposes (NTP, 1992)Published reference
Melting Point152 - 155 CInterpreted
Flash Point100 °CPublished reference
Solubility (water)greater than or equal to 100 mg/mL at 72 °F (NTP, 1992)Published reference

Regulatory & Transport

DOT / 49 CFR

UN Number
Not regulatedAdjudicated
Hazard Class
Not regulatedAdjudicated
Packing Group
Not regulatedAdjudicated
Proper Shipping Name
Not regulatedAdjudicated

GHS / OSHA HazCom 2012

Signal Word
WarningAdjudicated
H-Codes (Hazard Statements)
H319, H335Adjudicated
P-Codes (Precautionary Statements)
P261, P264, P271, P280, P304+P340, P305+P351+P338, P314, P337+P313, P403+P233, P405, P501Adjudicated

Occupational Exposure Limits

OSHA PEL (29 CFR 1910.1000)
no canonical
ACGIH TLV
no canonical
NIOSH REL
no canonical
NIOSH IDLH
no canonical

Transport descriptions reflect 49 CFR 172.101 lookup at time of publication. Sourced data: ECHA CLP Annex VI for harmonised classifications, NIOSH Pocket Guide for REL/IDLH, OSHA Z-Tables for PEL. Always verify against the latest regulatory text before shipment-critical decisions.

Supplier Qualification Packet

One zipped download containing the TDS, SDS, latest lot COA (when available), and a fresh Letter of Continuing Guaranty for Citric Acid Anhydrous - ACS Reagent Grade. Every file included is SHA-256 hashed and listed in a manifest your QA team can audit.

Download audit packet

Applications

  • Industrial use in the manufacture of ecologically compatible detergents, chemical cleaning, concrete admixtures and plasticizersingredi.com
  • Used as a hydraulic fracturing / well stimulation chemical in oil and shale gas productionmubychem.com

Applications are drawn from published manufacturer and supplier documentation; each is sourced. Suitability for a specific use is the buyer's to confirm.

Storage & Handling

Recommended Storage
Store at 15-25 °Clobachemie.com
Handling Precautions
Use standard chemical PPE — splash goggles, gloves, lab coat. Refer to SDS for hazard-specific PPE requirements.Class-level guidance — not product-specific; the SDS controls.
Incompatibilities
Consult the SDS for material-specific incompatibilities.Class-level guidance — not product-specific; the SDS controls.
Shelf Life
60 monthslobachemie.comStore at 15-25 °C

For full hazard, PPE, and emergency response guidance, refer to the Safety Data Sheet (SDS) for this product. The SDS controls in all cases where guidance differs.

Packaging & Logistics

Shipping Description (US DOT)

Not regulated for transport.

Confirm against shipping documents and carrier requirements before tender.

NMFC Class
55

Freight classification is a fallback estimate. Verify with carrier before tender.

Revision History

Last reviewed 2026-07-17 by Andre Taki, DOT Hazmat Specialist.

VersionDateChangeTrigger
1.12026-07-17Canonical data re-verified: 10 fields updated against independent vendor SDSs, CLP Annex VI, 49 CFR, and OSHA HazCom 2024 (GHS classification, hazard/precautionary codes, signal word, physical properties as applicable).
  • countryOfOrigin· canonical adjudication / reground (coa.data_provenance)
  • dotProperShippingName· canonical adjudication / reground (coa.data_provenance)
  • dotSubsidiaryHazardClass· canonical adjudication / reground (coa.data_provenance)
  • ghsClassification· canonical adjudication / reground (coa.data_provenance)
  • hazard_h_codes· canonical adjudication / reground (coa.data_provenance)
  • hazard_p_codes· canonical adjudication / reground (coa.data_provenance)
  • hsCode· canonical adjudication / reground (coa.data_provenance)
  • packingGroup· canonical adjudication / reground (coa.data_provenance)
  • physicalProperties· canonical adjudication / reground (coa.data_provenance)
  • unNumber· canonical adjudication / reground (coa.data_provenance)
canonical_change
1.02026-05-20Initial URL-first TDS published from canonical chemistry registry.initial

This Technical Data Sheet is provided for technical reference. The Safety Data Sheet (SDS) controls in all cases where guidance differs. Values reflect Alliance Chemical canonical data at time of generation; subsequent revisions are recorded in the Revision History above.