Industrial chemicals · Taylor, TX
Technical Data Sheet

Technical Data Sheet

Methanol Technical Grade

Technical Grade

CAS Number
67-56-1
Alliance Code
methanol-technical-grade
Generated
2026-08-31
Revision
1.3
Reviewed
2026-06-18 · Andre Taki
2D chemical structure of Methanol Technical Grade
Structure · PubChem
Last reviewed 2026-06-18 by Andre Taki, DOT Hazmat Specialist.

Identity & Composition

Product Name
Methanol Technical Grade
Alliance Code
methanol-technical-grade
Grade
Technical Grade
Concentration
CAS Number
67-56-1PubChem
Formula
CH4OPubChem
Molecular Weight
32.042PubChem
Product Type
pure_substance

Specifications

TestSpecificationTypicalMethodSource
Purity (CH3OH), wt % on dry basis99.85 Min99.95 % W/WIMPCA 001-14Supplier specification
Acetone30 Max mg/kg3 mg/kgIMPCA 001-14Supplier specification
Acidity as acetic acid30 Max mg/kg5 mg/kgASTM D 1613-12Supplier specification
AlkalinityMax 0.0003 wt%0.00005 wt%Supplier specification
Carbonisable substances (sulfuric acid wash test), Pt-Co scale30 Max5ASTM E 346-08Supplier specification
Chloride as Cl0.5 Max mg/kg0.1 mg/kgIMPCA 002-98Supplier specification
Ethanol50 Max mg/kg20 mg/kgIMPCA 001-14Supplier specification
HydrocarbonsPass TestPasses testASTM D 1722-09Supplier specification
Iron in solution0.1 Max mg/kg0.02 mg/kgASTM E 394-09Supplier specification
IBP @ 760 mm HgMax 64.7°C64.5°CSupplier specification
Potassium permanganate time test at 15°C50 MINUTES min75ASTM D 1363-11Supplier specification
Non-volatile matter8 Max mg/1000 mL2ASTM D 1353-13Supplier specification
Carbonizable substancesMax 50, Pt-Co Scale15Supplier specification
Sulphur0.5 Max mg/kg0.1 mg/kgASTM D 3961-98 or ASTM D 5453-12Supplier specification
Total SulfurMax 0.5 ppm0.1 ppmSupplier specification
Water0.100 Max % w/w0.05 % W/WASTM E 1064-12Supplier specification

Specification values are guaranteed limits. Typical values are representative of production lots and are not guaranteed. Lot-specific certificates of analysis ship with every order.

Available GradesSame CAS, alternate grades and concentrations

GradeConcentrationTypical AssaySKUTDS
This grade Technical Gradecurrentcurrent
ACS Reagentmethanol-acs-reagent-gradeView TDS →

Typical assay shown is the rolling-window mean from the sibling product's most recent lots. Grade selection drives downstream end-use — verify the sibling grade matches your specification before substitution.

Physical & Chemical Properties

PropertyValueSource
AppearanceClear & Free of suspended matterSupplier specification
FormLiquidPublished reference
Color5 MaxSupplier specification
OdorCharacteristic, non-residualInterpreted
Specific Gravity (20 °C)0.7910 – 0.7930Supplier specification
Density0.792 at 68 °F (USCG, 1999) - Less dense than water; will floatPublished reference
Boiling Point1.0°C to include 64.6°±0.1° MaxSupplier specification
Melting Point-144 °F (NTP, 1992)Published reference
Flash Point52 °F (NTP, 1992)Published reference
Vapor Pressure100 mmHg at 70.2 °F ; 237.87 mmHg at 100 °F (NTP, 1992)Published reference
Solubility (water)greater than or equal to 100 mg/mL at 70 °F (NTP, 1992)Published reference

Polar solvent — purity vs. intended end-use (electronics, pharma, general industrial) is the dominant grade consideration. See application guidance for grade selection.

Materials of Construction

MaterialRatingConditionsSource
HDPECompatibleMethanol ACS/HPLC grade, assay min. 99.8% (typical 99.99%), supplied in 20 liter HDPE packaging; source states no upper temperature or exposure-time boundnwsci.com

Compatibility is drawn from published manufacturer and supplier documentation for this product; each rating is sourced. Confirm against your specific duty cycle before equipment selection.

Materials Selection Tool

Showing 13 of 13 materials compatible at the selected envelope.

MaterialRatingMax T (°C)Notes
Buna-N (NBR)
elastomer
Fair60Acceptable for alcohols; poor for ketones.
EPDM
elastomer
FairGood for alcohols, poor for esters
Viton (FKM)
elastomer
Fair80Swells in acetone and esters; avoid for those.
FFKM (Kalrez)
fluoropolymer
Excellent200Premium ester / ketone sealing
PTFE
fluoropolymer
Excellent200Universal solvent compatibility.
Borosilicate Glass
glass ceramic
Excellent100Universally inert.
Glass (borosilicate)
glass ceramic
Excellent100Inert
316L Stainless Steel
metal
Excellent80Inert; preferred for high-purity solvent service.
Aluminium
metal
Good40Acceptable; avoid prolonged wet contact
Carbon Steel
metal
Fair50Trace moisture causes rust; flash-rust prevention required.
HDPE
thermoplastic
Fair40Swells with many polar solvents; verify per solvent.
PP
thermoplastic
Good50Acceptable but watch swelling with esters
PVC
thermoplastic
Fair25Esters soften PVC; avoid for esters

Regulatory & Transport

DOT / 49 CFR

UN Number
UN123049 CFR 172.101
Hazard Class
3Adjudicated
Packing Group
IIAdjudicated
Proper Shipping Name
MethanolAdjudicated

GHS / OSHA HazCom 2012

Signal Word
DangerAdjudicated
H-Codes (Hazard Statements)
H225, H301, H311, H331, H370ECHA CLP Annex VI
P-Codes (Precautionary Statements)
P210, P233, P240, P241, P242, P243, P260, P264, P270, P271, P280, P301+P310, P302+P352, P303+P361+P353, P304+P340, P307+P311, P308+P311, P312, P321, P330, P361, P370+P378, P403+P233, P403+P235, P405, P501ECHA CLP Annex VI

Occupational Exposure Limits

OSHA PEL (29 CFR 1910.1000)
200 ppm TWAOSHA 29 CFR 1910.1000
ACGIH TLV
no canonical
NIOSH REL
200 ppm TWA / 250 ppm STELNIOSH Pocket Guide
NIOSH IDLH
6000 ppmNIOSH Pocket Guide

Transport descriptions reflect 49 CFR 172.101 lookup at time of publication. Sourced data: ECHA CLP Annex VI for harmonised classifications, NIOSH Pocket Guide for REL/IDLH, OSHA Z-Tables for PEL. Always verify against the latest regulatory text before shipment-critical decisions.

Supplier Qualification Packet

One zipped download containing the TDS, SDS, latest lot COA (when available), and a fresh Letter of Continuing Guaranty for Methanol Technical Grade. Every file included is SHA-256 hashed and listed in a manifest your QA team can audit.

Download audit packet

Catalog EquivalentsCross-reference vs major chemical suppliers

Sigma-Aldrich

SKUGradeConc.MatchNotes
179337ACS Reagent99.9%ExactACS Reagent ≥99.9%

Cross-references are informational. Confirm against the manufacturer's current specification before substitution. Competitor trademarks are property of their respective owners.

Application Guidance

Methanol Technical Grade (Technical Grade) is a polar solvent. Grade selection (technical, ACS, electronics, USP) determines acceptable residue and impurity levels for the intended end-use.

  • Cleaning and degreasing (technical-grade)
  • Coatings, inks, and adhesives formulation
  • Reaction solvent for chemical synthesis
  • Pharmaceutical manufacturing (USP-grade)
  • Electronics-grade cleaning and rinse applications

Flammable. Bond and ground equipment during transfer. Verify grade matches end-use specification before substitution.

Storage & Handling

Recommended Storage
Cool, well-ventilated flammable-liquid storage area. Tightly sealed original containers. Segregate from oxidizers and acids. Bond and ground bulk storage.Class-level guidance — not product-specific; the SDS controls.
Handling Precautions
Use chemical-resistant gloves and splash goggles. Bond and ground during transfer to prevent static accumulation. Eliminate ignition sources within vapor envelope.Class-level guidance — not product-specific; the SDS controls.
Incompatibilities
Strong oxidizers, strong acids, isocyanates, anhydrides. Hygroscopic — protect from atmospheric moisture for water-sensitive end uses.Class-level guidance — not product-specific; the SDS controls.
Shelf Life
Consult Technical Services for product-specific shelf life

For full hazard, PPE, and emergency response guidance, refer to the Safety Data Sheet (SDS) for this product. The SDS controls in all cases where guidance differs.

Packaging & Logistics

Shipping Description (US DOT)

UN1230, Methanol, 3, PG II

Sourced from 49 CFR 172.101. Confirm against shipping documents and carrier requirements before tender.

NMFC Class
70
Placard
Flammable Liquid
Packing Group
PG II

Revision History

Last reviewed 2026-06-18 by Andre Taki, DOT Hazmat Specialist.

VersionDateChangeTrigger
1.32026-08-05Canonical data updated: 4 fields changed via the provenance/adjudication pipeline.
  • hazardClass· canonical change (coa.data_provenance / adjudication)
  • packingGroup· canonical change (coa.data_provenance / adjudication)
  • signalWord· canonical change (coa.data_provenance / adjudication)
  • unNumber· canonical change (coa.data_provenance / adjudication)
canonical_change
1.22026-07-22Canonical data updated: 2 fields changed via the provenance/adjudication pipeline.
  • dotSubsidiaryHazardClass· canonical change (coa.data_provenance / adjudication)
  • dotProperShippingName· canonical change (coa.data_provenance / adjudication)
canonical_change
1.12026-06-18Canonical data re-verified: 3 fields updated against independent vendor SDSs, CLP Annex VI, 49 CFR, and OSHA HazCom 2024 (GHS classification, hazard/precautionary codes, signal word, physical properties as applicable).
  • countryOfOrigin· canonical adjudication / reground (coa.data_provenance)
  • ghsClassification· canonical adjudication / reground (coa.data_provenance)
  • hsCode· canonical adjudication / reground (coa.data_provenance)
canonical_change
1.02026-05-20Initial URL-first TDS published from canonical chemistry registry.initial

This Technical Data Sheet is provided for technical reference. The Safety Data Sheet (SDS) controls in all cases where guidance differs. Values reflect Alliance Chemical canonical data at time of generation; subsequent revisions are recorded in the Revision History above.