Industrial chemicals · Taylor, TX
Technical Data Sheet

Technical Data Sheet

Perchloroethylene ACS Grade

ACS Grade

Alliance Code
perchloroethylene-acs-grade
Reviewed
2026-07-17
Revision
1.10
CAS number
127-18-4
UN number
UN1897
Hazard class · packing group
6.1 · PG III
Structure
2D chemical structure of Perchloroethylene ACS Grade
Structure · PubChem
Grade
ACS Grade
Signal word
Danger
Hazards
Irritant / harmfulHealth hazardEnvironmental hazardH315 H317 H319 H336 H350 H370 H373 H411
Proper shipping name
Tetrachloroethylene
Last reviewed 2026-07-17 by Andre Taki, Chief Commercial Officer.

Identity & Composition

Product Name
Perchloroethylene ACS Grade
Alliance Code
perchloroethylene-acs-grade
Grade
ACS Grade
Concentration
—
CAS Number
127-18-4PubChem
Formula
—PubChem
Molecular Weight
—PubChem
Product Type
Pure substance

Specifications

TestSpecificationTypicalMethodSource
Assay (C2Cl4)≥99.0% C2Cl499.97 %Gas chromatography; Type I, methyl silicone columnInterpreted
Color (APHA)APHA: ≤105—Interpreted
Residue after evaporation≤0.0005 %0.00009 %—Interpreted
Ultraviolet absorbance at 300 nm1.0 AU1.0 AUUltraviolet SpectrophotometryInterpreted
Ultraviolet absorbance at 305 nm0.2 AU0.2 AUUltraviolet SpectrophotometryInterpreted
Ultraviolet absorbance at 350 nm0.05 AU0.05 AUUltraviolet SpectrophotometryInterpreted
Ultraviolet absorbance at 400 nm0.03 AU0.03 AUUltraviolet SpectrophotometryInterpreted
Water (H2O)≤0.05 %0.009 %—Interpreted
Identification (FTIR)Conforms to reference spectrum of tetrachloroethylenePasses testFTIR-ATR, comparison to reference spectrumInterpreted
Titrable acid0.0005 meq/g max.0.000020 meq/gPotentiometric titration with 0.01 N NaOHInterpreted
Free halogens (as Cl)Passes testPasses testPotassium iodide - starch testInterpreted

Values are reproduced from the current product reference. Source labels do not by themselves establish a supplier guarantee or a test result for your lot. Confirm applicable acceptance limits and request lot-specific documentation.

Physical & Chemical Properties

PropertyValueSource
AppearanceColorless, volatile liquidAdjudicated
FormLiquidPublished reference
OdorEther-like odorPublished reference
Specific Gravity1.62 at 25 °C (water = 1); sinks in waterAdjudicated
Density1.619 - 1.626 g/mLInterpreted
Boiling Point121 °C (250 °F) at 760 mmHgAdjudicated
Melting Point-22 to -19 °C (-8 to -2 °F)Adjudicated
Flash PointNo flash point in conventional closed tester.Published reference
Vapor Pressure13–14 mmHg (1.7–1.8 kPa) at 20 °CAdjudicated
Vapor Density5.8 (air = 1)Adjudicated
Solubility (water)0.15 g/L in water at 20 °C (practically insoluble)Adjudicated
Refractive Index (nD 20)1.5045 - 1.5065Interpreted
Viscosity0.89 mPa·s at 20 °CAdjudicated

Materials of Construction

MaterialRatingConditionsSource
stainless steelCompatibleneat perchloroethylene as shipped in bulk; source states no concentration or temperature limitoxychem.com

Compatibility is drawn from published manufacturer and supplier documentation for this product; each rating is sourced. Confirm against your specific duty cycle before equipment selection.

Regulatory & Transport

DOT / 49 CFR

UN Number
UN189749 CFR 172.101
Hazard Class
6.1Adjudicated
Packing Group
IIIAdjudicated
Proper Shipping Name
TetrachloroethyleneAdjudicated

GHS / OSHA HCS 2024

Signal Word
DangerAdjudicated
H-Codes (Hazard Statements)
H315, H317, H319, H336, H350, H370, H373, H411Adjudicated
P-Codes (Precautionary Statements)
P201, P202, P260, P264, P270, P272, P273, P280, P302+P352, P305+P351+P338, P308+P311, P308+P313, P312, P314, P321, P332+P313, P333+P313, P337+P313, P362, P391, P405, P501Adjudicated

Occupational Exposure Limits

OSHA PEL (29 CFR 1910.1000)
100 ppm TWA / 200 ppm acceptable ceiling / 300 ppm 5-min peakOSHA 29 CFR 1910.1000
ACGIH TLV
25 ppm TWA / 100 ppm STEL (A3: confirmed animal carcinogen)Adjudicated
NIOSH REL
Ca (carcinogen — minimize occupational exposure)NIOSH Pocket Guide
NIOSH IDLH
150 ppmNIOSH Pocket Guide

Transport descriptions reflect 49 CFR 172.101 lookup at time of publication. Sourced data: NIOSH Pocket Guide for REL/IDLH, OSHA Z-Tables for PEL. Always verify against the latest regulatory text before shipment-critical decisions.

Health & Fire Hazard

Acute Toxicology

LD₅₀ Oral (rat)
2,629 mg/kgAdjudicated
LD₅₀ Dermal (rabbit)
> 3,228 mg/kgAdjudicated
LC₅₀ Inhalation (rat, 4 h)
27.8 mg/L (vapor)Adjudicated

Acute toxicology values from SDS Section 11 or NIOSH RTECS.

Supplier Qualification Packet

One zipped download containing the TDS, SDS, latest lot COA (when available), and a fresh Letter of Continuing Guaranty for Perchloroethylene ACS Grade. Every file included is SHA-256 hashed and listed in a manifest your QA team can audit.

Download audit packet

Applications

Industrial solvent and chemical intermediate, only for the uses still permitted under TSCA section 6 (40 CFR Part 751); see Section 15.Adjudicated

Restrictions on Use: After December 8, 2026 this chemical substance (as defined in TSCA section 3(2))/product cannot be distributed in commerce to retailers for any use. After March 8, 2027, this chemical substance (as defined in TSCA section 3(2))/product is and can only be distributed in commerce or processed with a concentration of PCE equal to or greater than 0.1% by weight for the following purposes: (1) Processing as a reactant/intermediate; (2) Processing into formulation, mixture or reaction product; (3) Processing by repackaging; (4) Recycling; (5) Industrial and commercial use as solvent in open-top batch vapor degreasing; (6) Industrial and commercial use as solvent in closed-loop batch vapor degreasing; (7) Industrial and commercial use in maskant for chemical milling; (8) Industrial and commercial use as a processing aid in catalyst regeneration in petrochemical manufacturing; (9) Industrial and commercial use as a processing aid in sectors other than petrochemical manufacturing; (10) Industrial and commercial use as solvent for cold cleaning of tanker vessels; (11) Industrial and commercial use as energized electrical cleaner; (12) Industrial and commercial use in laboratory chemicals; (13) Industrial and commercial use in solvent-based adhesives and sealants; (14) Industrial and commercial use in dry cleaning in 3rd generation machines until December 20, 2027; (15) Industrial and commercial use in all dry cleaning and related spot cleaning until December 19, 2034; (16) Export; and (17) Disposal.

Storage & Handling

Recommended Storage
Keep containers tightly closed in a cool, dry, well-ventilated place, protected from sunlight and moisture. Do not store in aluminum containers. Keep away from strong bases, reactive metals and oxidizers. Store locked up.Adjudicated
Handling Precautions
Use standard chemical PPE — splash goggles, gloves, lab coat. Refer to SDS for hazard-specific PPE requirements.Class-level guidance — not product-specific; the SDS controls.
Incompatibilities
Strong oxidizers, strong acids and bases, reactive and finely divided metals (aluminum, zinc, alkali metals), amines, peroxides, oxygen.Adjudicated
Shelf Life
Consult Technical Services for product-specific shelf life

For full hazard, PPE, and emergency response guidance, refer to the Safety Data Sheet (SDS) for this product. The SDS controls in all cases where guidance differs.

Packaging & Logistics

Shipping Description (US DOT)

UN1897, Tetrachloroethylene, 6.1, PG III

Sourced from 49 CFR 172.101. Confirm against shipping documents and carrier requirements before tender.

NMFC Class
70
Placard
Toxic
Packing Group
PG III

Revision History

Last reviewed 2026-07-17 by Andre Taki, Chief Commercial Officer, DOT Hazmat–certified (49 CFR 172.704).

VersionDateChangeTrigger
1.102026-10-13Canonical data updated: 1 field changed via the provenance/adjudication pipeline.
  • storage_precautions· canonical change (coa.data_provenance / adjudication)
canonical_change
1.92026-10-08Canonical data updated: 3 fields changed via the provenance/adjudication pipeline.
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canonical_change
1.82026-10-07Canonical data updated: 3 fields changed via the provenance/adjudication pipeline.
  • ghsClassification· canonical change (coa.data_provenance / adjudication)
  • hazard_h_codes· canonical change (coa.data_provenance / adjudication)
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canonical_change
1.72026-10-06Canonical data updated: 20 fields changed via the provenance/adjudication pipeline.
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1.62026-10-05Canonical data updated: 2 fields changed via the provenance/adjudication pipeline.
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1.52026-09-30Canonical data updated: 3 fields changed via the provenance/adjudication pipeline.
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1.42026-08-05Canonical data updated: 1 field changed via the provenance/adjudication pipeline.
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1.32026-07-22Canonical data updated: 2 fields changed via the provenance/adjudication pipeline.
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1.22026-07-17Canonical data updated: 4 fields changed via the provenance/adjudication pipeline.
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canonical_change
1.12026-07-17Canonical data re-verified: 6 fields updated against independent vendor SDSs, CLP Annex VI, 49 CFR, and OSHA HazCom 2024 (GHS classification, hazard/precautionary codes, signal word, physical properties as applicable).
  • countryOfOrigin· canonical adjudication / reground (coa.data_provenance)
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canonical_change
1.02026-05-20Initial URL-first TDS published from canonical chemistry registry.initial

This Technical Data Sheet is provided for technical reference. The Safety Data Sheet (SDS) controls in all cases where guidance differs. Values reflect Alliance Chemical canonical data at time of generation; subsequent revisions are recorded in the Revision History above.