Industrial chemicals · Taylor, TX
Technical Data Sheet

Technical Data Sheet

Sodium Bisulfite 25% ACS Grade

ACS · 25%

Alliance Code
sodium-bisulfite-25-acs-grade
Reviewed
2026-10-13
Revision
1.6
CAS number
7631-90-5
UN number
UN2693
Hazard class · packing group
8 · PG III
Structure
2D chemical structure of Sodium Bisulfite 25% ACS Grade
Structure · PubChem
Grade
ACS · 25%
Signal word
Danger
Hazards
CorrosiveIrritant / harmfulEUH031 H302 H318
Proper shipping name
Bisulfites, aqueous solutions, n.o.s. (Sodium bisulfite)
Last reviewed 2026-10-13.

Identity & Composition

Product Name
Sodium Bisulfite 25% ACS Grade
Alliance Code
sodium-bisulfite-25-acs-grade
Grade
ACS
Concentration
25%
CAS Number
7631-90-5Adjudicated
Formula
HNaO3SAdjudicated
Molecular Weight
104.06Adjudicated
Product Type
Solution

Specifications

TestSpecificationTypicalMethodSource
Assay24.0 - 26.0 %24.9 %—Interpreted
Chloride (Cl)0.005 % max0.00021 %—Interpreted
Heavy metals (as Pb)0.00025 % max0.000068 %—Interpreted
Insoluble matter0.0013 % max0.00024 %—Interpreted
Iron (Fe)0.0005 % max0.000081 %—Interpreted
Composition25 % sodium hydrogen sulfite in deionized water, by weightConformsBy formulation; confirmed by specific gravityInterpreted

Values are reproduced from the current product reference. Source labels do not by themselves establish a supplier guarantee or a test result for your lot. Confirm applicable acceptance limits and request lot-specific documentation.

Available GradesSame CAS, alternate grades and concentrations

GradeConcentrationTypical AssaySKUTDS
This grade ACS25%—currentcurrent
ACS Grade40%—sodium-bisulfite-40-acs-gradeView TDS →
Technical40%—sodium-bisulfite-40View TDS →
Technical25%—sodium-bisulfite-25View TDS →
Technical15%—sodium-bisulfite-15-technical-gradeView TDS →
ACS10%—sodium-bisulfite-10-acs-gradeView TDS →
Technical10%—sodium-bisulfite-10-technical-gradeView TDS →
ACS——sodium-bisulfite-15-acs-gradeView TDS →

Typical assay shown is the rolling-window mean from the sibling product's most recent lots. Grade selection drives downstream end-use — verify the sibling grade matches your specification before substitution.

Physical & Chemical Properties

PropertyValueSource
AppearanceClear, colorless to light-yellow liquidPublished reference
FormLiquidPublished reference
OdorSlight sulfur dioxide odorPublished reference
pH3.5-5.0Published reference
Specific Gravity~1.20Published reference
Density~1.18-1.22 g/cm³ (25%, 20°C)Published reference
Boiling Point100 to 103 °C (212 to 217 °F) (aqueous solution)Adjudicated
Melting Point-9 to 0 °C (16 to 32 °F), freezing point (aqueous solution)Adjudicated
Flash PointNot applicable (non-combustible aqueous solution)Published reference
Solubility (water)Miscible with waterPublished reference

Regulatory & Transport

DOT / 49 CFR

UN Number
UN2693Adjudicated
Hazard Class
8Adjudicated
Packing Group
IIIAdjudicated
Proper Shipping Name
Bisulfites, aqueous solutions, n.o.s. (Sodium bisulfite)Adjudicated

GHS / OSHA HCS 2024

Signal Word
DangerAdjudicated
H-Codes (Hazard Statements)
EUH031, H302, H318Adjudicated
P-Codes (Precautionary Statements)
P264, P270, P280, P301+P312, P305+P351+P338, P310, P330, P501Adjudicated

Occupational Exposure Limits

OSHA PEL (29 CFR 1910.1000)
—no canonical
ACGIH TLV
—no canonical
NIOSH REL
5 mg/m³ TWANIOSH Pocket Guide
NIOSH IDLH
—no canonical

Transport descriptions reflect 49 CFR 172.101 lookup at time of publication. Sourced data: NIOSH Pocket Guide for REL/IDLH, OSHA Z-Tables for PEL. Always verify against the latest regulatory text before shipment-critical decisions.

Supplier Qualification Packet

One zipped download containing the TDS, SDS, latest lot COA (when available), and a fresh Letter of Continuing Guaranty for Sodium Bisulfite 25% ACS Grade. Every file included is SHA-256 hashed and listed in a manifest your QA team can audit.

Download audit packet

Application Guidance

Sodium Bisulfite 25% ACS Grade (ACS) application guidance is available on request. Contact Alliance Chemical Technical Services for grade-specific use recommendations.

    Storage & Handling

    Recommended Storage
    Keep tightly closed in a cool, ventilated area in polyethylene, fiberglass or stainless-steel containers, away from acids and oxidizers. Protect from freezing (crystallizes near 5 °C).Adjudicated
    Handling Precautions
    Use standard chemical PPE — splash goggles, gloves, lab coat. Refer to SDS for hazard-specific PPE requirements.Class-level guidance — not product-specific; the SDS controls.
    Incompatibilities
    Acids (release toxic sulfur dioxide gas); oxidizing agents; nitrites and nitrates.Adjudicated
    Shelf Life
    Consult Technical Services for product-specific shelf life

    For full hazard, PPE, and emergency response guidance, refer to the Safety Data Sheet (SDS) for this product. The SDS controls in all cases where guidance differs.

    Packaging & Logistics

    Shipping Description (US DOT)

    UN2693, Bisulfites, aqueous solutions, n.o.s. (Sodium bisulfite), 8, PG III

    Sourced from 49 CFR 172.101. Confirm against shipping documents and carrier requirements before tender.

    NMFC Class
    65
    Placard
    Corrosive
    Packing Group
    PG III

    Revision History

    VersionDateChangeTrigger
    1.62026-10-13Canonical data updated: 4 fields changed via the provenance/adjudication pipeline.
    • storage_precautions· canonical change (coa.data_provenance / adjudication)
    • incompatible_materials· canonical change (coa.data_provenance / adjudication)
    • conditions_to_avoid· canonical change (coa.data_provenance / adjudication)
    • hazardous_decomposition_products· canonical change (coa.data_provenance / adjudication)
    canonical_change
    1.52026-10-08Canonical data updated: 3 fields changed via the provenance/adjudication pipeline.
    • ghsClassification· canonical change (coa.data_provenance / adjudication)
    • hazard_h_codes· canonical change (coa.data_provenance / adjudication)
    • hazard_p_codes· canonical change (coa.data_provenance / adjudication)
    canonical_change
    1.42026-10-07Canonical data updated: 3 fields changed via the provenance/adjudication pipeline.
    • ghsClassification· canonical change (coa.data_provenance / adjudication)
    • hazard_h_codes· canonical change (coa.data_provenance / adjudication)
    • hazard_p_codes· canonical change (coa.data_provenance / adjudication)
    canonical_change
    1.32026-10-05Canonical data updated: 1 field changed via the provenance/adjudication pipeline.
    • oel_niosh_rel· canonical change (coa.data_provenance / adjudication)
    canonical_change
    1.22026-09-30Canonical data updated: 2 fields changed via the provenance/adjudication pipeline.
    • boilingPoint· canonical change (coa.data_provenance / adjudication)
    • meltingPoint· canonical change (coa.data_provenance / adjudication)
    canonical_change
    1.12026-07-22Canonical data updated: 1 field changed via the provenance/adjudication pipeline.
    • dotSubsidiaryHazardClass· canonical change (coa.data_provenance / adjudication)
    canonical_change

    This Technical Data Sheet is provided for technical reference. The Safety Data Sheet (SDS) controls in all cases where guidance differs. Values reflect Alliance Chemical canonical data at time of generation; subsequent revisions are recorded in the Revision History above.